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A new method is introduced for the preparation of graphene/polyaniline hybrids using a one-step intercalation polymerization of aniline inside the expanded graphite. The structural and morphological characterizations were performed by X-ray diffraction analysis, transmission electron microscopy and field emission scanning electron microscopy. Both the experimental and first-principles simulated results show that the aniline cation formed by aniline and H(+) tends to be drawn towards the electron-enriched zone and to intercalate into the interlayer of graphite. Subsequently, an in situ polymerization leads to the separation of graphite into graphene sheet, resulting from the exothermic effect and more vigorous movements of the chain molecules of polyaniline. The interactions between polyaniline and graphene were confirmed by Fourier transform infrared spectroscopy and Raman spectra. In addition, the graphene/polyaniline hybrid exhibited a breakthrough in the improvement of microwave absorption.

Strain sensors that are capable of monitoring complex human motions with high accuracy are highly desirable for developing wearable electronics. This paper reports the fabrication of highly stretchable and sensitive multidirectional strain sensors with tunable strain gauge factors by employing a digitally controlled printer to incorporate carbon nanotube (CNT) layers into polydimethylsiloxane (PDMS) substrates. The fabricated sensors exhibit a high stretchability (up to 45%) and sensitivity with a gauge factor of 35.75. The gauge factors could be easily modulated by tuning the number of CNT printing cycles to accommodate diverse requirements. The cyclic loading-unloading test results revealed that the composite strain sensors exhibited excellent long-term durability. Particularly, in this work, for the first time, human-motion-induced strain was measured by a motion capture system and compared with the strain data obtained from the fabricated strain sensors. The deviation of strains measured by composite sensors is less than 20%, indicating the great accuracy of CNT/PDMS sensors to quantify the amount of motion-induced strain. Of significant importance is that due to the flexibility of the printing technique used, rosette-type sensors were fabricated to simultaneously measure strains along multiple axes. These superior sensing capabilities of the fabricated CNT/PDMS strain sensors give them great application potential in motion-detecting systems.

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