Manipulating functional stimuli-responsive materials has been a hot topic in the research of smart sensors and anticounterfeiting encryption. Here, a novel functional chiral nematic cellulose nanocrystal (CNC) film showing dual responsiveness to humidity and formaldehyde gas was fabricated. The chiral nematic CNC iridescent film could respond to environmental humidity and formaldehyde gas changes by reversible motion. Interestingly, the humidity sensitivity of the CNC iridescent film could be gated by exposing the film to formaldehyde gas. At the same time, the formaldehyde-responsive behavior is strongly affected by the relative humidity (RH), and the response range could be tuned by changing the RH over a wide range. Importantly, the formaldehyde-induced color change could be altered from invisible to visible by the naked eye when the film was exposed to a humid environment. The mechanism of this dual response of the CNC iridescent film is ascribed to the synergistic effect of cooperation and competition between water and formaldehyde molecules by constructing physical cross-linking networks by hydrogen bonds among water, formaldehyde, and CNCs. Furthermore, the “RH-concentration of formaldehyde gas-color” ternary colorimetric system was simulated, which is thought to endow the CNC iridescent film with great potential to act as a sensor in the convenient visible detection of gaseous formaldehyde. Furthermore, this work provided a promising strategy to design multi-gas-sensitive devices with convenient detection, good stability, and excellent reversibility.

The integrated microwave photonic filter (MPF), as a compelling candidate for next-generation radio-frequency (RF) applications, has been widely investigated for decades. However, most integrated MPFs reported thus far have merely incorporated passive photonic components onto a chip-scale platform, while all necessary active devices are still bulk and discrete. Though few attempts to higher photonic integration of MPFs have been executed, the achieved filtering performances are fairly limited, which impedes the pathway to practical deployments. Here, we demonstrate, for the first time to our knowledge, an all-integrated MPF combined with high filtering performances, through hybrid integration of an InP chip-based laser and a monolithic silicon photonic circuit consisting of a dual-drive Mach–Zehnder modulator, a high- Q ring resonator, and a photodetector. This integrated MPF exhibits a high spectral resolution as narrow as 360 MHz, a wide-frequency tunable range covering the S-band to K-band (3 to 25 GHz), and a large rejection ratio of > 40    dB . Moreover, the filtering response can be agilely switched between the bandpass and band-stop function with a transient respond time ( ∼ 48    μs ). Compared with previous MPFs in a similar integration level, the obtained spectral resolution in this work is dramatically improved by nearly one order of magnitude, while the valid frequency tunable range is broadened more than twice, which can satisfy the essential filtering requirements in actual RF systems. As a paradigm demonstration oriented to real-world scenarios, high-resolution RF filtering of realistic microwave signals aiming for interference rejection and channel selection is performed. Our work points out a feasible route to a miniaturized, high-performance, and cost-effective MPF leveraging hybrid integration approach, thus enabling a range of RF applications from wireless communication to radar toward the higher-frequency region, more compact size, and lower power consumption.

The origin of sorption hysteresis in the wood-water system is still under debate. In nanoporous-fluid systems, in general, hysteresis is explained as the manifestation of metastable states in a single pore-fluid system and that is further complicated by the pore connectivity. Cell walls are considered as micro-mesoporous materials and capillary condensation in the entire hygroscopic region is proposed as an alternative sorption mechanism. In the present work, the woods of Douglas-fir, aspen and western red cedar were in focus and the pore connectivity has been investigated by observing five experimentally generated hysteresis patterns comprised by up to 4th scanning curves at 25 and 40°C. Special attention was given to the congruency property from one pattern as it is known from the literature that deviation from this property can reveal the extent of pore connectivity. Consistent patterns were found for the species-temperature combinations. Further, the high extent of congruency property indicated the dominance of independent cell wall pores.

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Molecular simulation has been successfully applied to sorption and hysteresis studies of various nanoporous materials, revealing underlying mechanisms that neither theoretical nor experimental approaches can achieve. In this work, the grand canonical Monte Carlo approach is used in a simplified wood-water system to simulate sorption isotherms and hysteresis at 25°C and 40°C. Wood is represented by a cell wall model composed of a solid substance and evenly distributed independent cylindrical nanopores with diameters in the range of 0.6–2.2 nm. Polysaccharides and lignin pore-wall compositions are considered. Hydroxyl groups are modeled as negative energy pits attached to walls and water is represented by the extended simple point charge model. Capillary condensation in the wide hygroscopic range and metastable states are well demonstrated in the simulations, thus supporting the independent domain model discussed in the first paper of this series. The size of simulated hysteresis loops increases with pore size, less hydrophilic lignin composition and reduced temperature. The trends shown by the model are consistent with experimental findings. The larger hysteresis can be explained by more metastable states due to weaker wall-water interaction or smaller thermal fluctuation.