The mesostructured NiO/Ni composites boost the electrochemical energy storage performance of NiO to its theoretical limit, which results from the synergism of high accessibility to electrolyte, short solid-state ion diffusion length and high conductivity owing to the unique mesostructure.

A convenient template-and surfactant-free strategy has been developed to prepare porous hierarchical Ni nanostructures by directly calcining the nickel-based flower-like precursor in Ar. The precursor is preformed by refluxing the solution of nickel nitrate and the co-precipitators of hexamethylenetetramine and oxalic acid at 100 C for 6 h. The unique Ni nanostructures are composed of porous sheets of several nanometers in thickness with a wide pore size distribution of 5-100 nm, with a Brunauer-Emmett-Teller specific surface area up to 24.5 m 2 g À1 . The formation process has been in situ examined by thermogravimetry-differential scanning calorimetry-mass spectroscopy, which illuminates the continuous generation of Ni species with the simultaneous release of gaseous species from decomposition and/or reduction of the precursor. Coupled with the good soft ferromagnetism, the porous Ni nanostructures with high surface area have great potential as a magnetically separable catalyst, as demonstrated in the excellent performance for the selective hydrogenation of acetophenone to 1-phenylethanol at 100 C.

No abstract

No abstract