Magnesium-ion batteries are fabricated with MgCo 2 O 4 /graphite composites as the cathode material. MgCo 2 O 4 nanoparticles are prepared using a co-precipitation method. A three-dimensional mixing process is utilized to mechanically decorate MgCo 2 O 4 nanoparticles on graphite particles. The MgCo 2 O 4 spinel crystals of size ranging from 20-70 nm on micrometer sized graphite chunks are analyzed by using X-ray diffraction and scanning electron microscopy. The electrochemical properties of the as-prepared composites are well characterized by cyclic voltammetry, charge and discharge cycling, and electrochemical impedance spectroscopy (EIS). Surprisingly, the MgCo 2 O 4 /graphite composite with a relatively low proportion of MgCo 2 O 4 , compared with the other as-prepared composites, achieves the highest specific capacity of 180 mAh g -1 at a C rate of 0.05 C. EIS results suggest that the electrical conductivity of the composite material is an increasing function of the graphite proportion. The superior performance of the MgCo 2 O 4 /graphite composite could be ascribed to the decoration of nanosized MgCo 2 O 4 particles as well as to the increased conductivity provided by graphite.
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