On-road mobile sources of emissions make important contributions to particulate matter pollution (PM2.5–PM10) in cities. The quantification of such pollution is, however, highly challenging due to the number of interacting factors that affect emissions such as vehicle category, emission standard, vehicle speed and weather conditions. The proper identification of individual sources of emission is particularly necessary for air quality management areas. In this study, we estimated exhaust and non-exhaust traffic-related PM2.5 and PM10 contributions to total ambient pollution in Banská Bystrica (Slovak republic) by simulation based on the AERMOD dispersion model. Emission rates of particular vehicle categories were obtained through vehicle population statistics, traffic data survey and emission factors from the EMEP/EEA air pollutant emission inventory guidebook. Continuous PM10 and PM2.5 data from air quality monitoring stations were analysed for the years 2019–2020 and compared with modelled concentrations. The annual concentration values of PM2.5 and PM10 in the study area reached 16.71 μg/m3 and 15.57 μg/m3, respectively. We found that modelled PM2.5 peak concentration values exceeded the WHO air quality guideline annual mean limit. Traffic-related PM2.5 and PM10 contributions to ambient pollution at the reference point located nearby to a busy traffic route were approximately 25% and 17%, respectively. The reference point located outside the main transport corridors showed an approximately 11% contribution, both for PM2.5 and PM10 concentrations. The simulations showed that PM pollution is greatly contributed to by on-road mobile sources of emissions in the study area, and especially non-exhaust emissions, which require serious attention in association with their health impacts and the selection of Banská Bystrica as an air quality management area.
In order to keep the home and occupational environment clean and non-infectious, the consumption of cleaners and disinfectants, including cosmetics, is increasing. Excessive use of these products results in their accumulation in the aquatic environment. Conventional wastewater treatment plants are unable to effectively remove the emergent pollutants, including personal care products. This article is focused on the monitoring of the presence of personal care products in surface waters in two river basins in the Slovak Republic, in terms of the surfactant content. Ecotoxicological evaluation of the selected samples from the monitored river basins was performed by an acute toxicity test using the test organism Daphnia magna. The monitoring results indicate the presence of personal care products in the aquatic environment which poses an ecological and environmental risk. Monitoring in the Hron and Nitra river basins confirmed contamination with the surfactants, to which the measures related to the COVID-19 pandemic contributed. The content of the surfactants in personal care products is significant, and their impact on the aquatic environment is not sufficiently monitored.
Workers in primary aluminum smelter are exposed to fluoride from cryolite (Na3AlF6) used in the electrolysis process. Post-shift urinary fluoride is considered as an appropriate index for examination of fluoride exposure. The objective of the study was to investigate the exposure to fluoride in primary aluminum smelter in Žiar nad Hronom (Slovakia) during three consecutive two-year periods between 2012 and 2018. The relationship between fluoride exposure in the occupational environment, tobacco smoking, and pre- and post-shift urinary fluoride concentration was investigated in 76 male workers in the ages from 21 to 60 years. Workers were monitored by personal fluoride sampling equipment. Their urinary samples were collected prior to the start and at the end of an eight-hour shift. Fluoride content in urine samples was analyzed by potentiometric ion-selective electrode and expressed as weight ratio of fluoride content to creatinine. The Mean ± SD particulate fluoride concentration in occupational air was 0.966 ± 1.658 mg/m3 and gas-phase fluoride concentration was 0.327 ± 0.809 mg/m3. Mean urinary fluoride concentration of all workers was significantly higher (p < 0.001) after the eight-hour shift. Smokers tended to have a higher post-shift mean urinary fluoride concentration than non-smokers, but this difference was not statistically significant (p = 0.11). The difference between these two groups of workers was also not statistically significant (p = 0.62) before the shift. Therefore, according to results, smoking caused no statistically significant difference in urinary fluoride levels between the group of smokers and group of non-smokers in primary aluminum workers.
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