Accurate and fast-convergent time synchronization is very important for wireless sensor networks. The flooding time synchronization converges fast, but its transmission delay and by-hop error accumulation seriously reduce the synchronization accuracy. In this paper, a rapid-flooding multiple oneway broadcast time-synchronization (RMTS) protocol for largescale wireless sensor networks is proposed. To minimize the byhop error accumulation, the RMTS uses maximum likelihood estimations for clock skew estimation and clock offset estimation, and quickly shares the estimations among the networks. As a result, the synchronization error resulting from delays is greatly reduced, while faster convergence and higher-accuracy synchronization is achieved. Extensive experimental results demonstrate that, even over 24-hops networks, the RMTS is able to build accurate synchronization at the third synchronization period, and moreover, the by-hop error accumulation is slower when the network diameter increases.

Ionized metal physical vapor deposition ͑IMPVD͒ is a process in which sputtered metal atoms from a magnetron target are ionized by a secondary plasma, accelerated into the substrate, and deposited with moderately anisotropic fluxes. The momentum and energy transfer from the sputtered metal atoms and ion-produced reflected neutrals to the background gas, sputter heating, produces rarefaction which influences the operating characteristics of the discharge. To address these processes, a model was developed to simulate the sputtering of metal atoms and their transport in IMPVD reactors. The model accounts for the ion-energy-dependent yield and kinetic energy of the sputtered and reflected atoms, and for sputter heating. The model was validated by comparing its results to experimentally measured metal atom densities and the ionization fraction of the deposition flux. Sputter heating as a function of auxiliary ionization and magnetron power in an inductively coupled plasma IMPVD reactor for Al deposition was then investigated. Sputter heating produces rarefaction of the buffer gas which results in a redistribution of Al species in the reactor compared to the absence of sputter heating. Consequently, the ionization fraction of the depositing metal flux decreases, while the magnitude of the flux increases. The minimum Ar density due to sputter heating is regulated by heat transfer to the target. The electron density increases significantly with the addition of a small amount of metal atoms to the plasma.

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