Spectral diffusion is a result of random spectral jumps of a narrow line as a
result of a fluctuating environment. It is an important issue in spectroscopy,
because the observed spectral broadening prevents access to the intrinsic line
properties. However, its characteristic parameters provide local information on
the environment of a light emitter embedded in a solid matrix, or moving within
a fluid, leading to numerous applications in physics and biology. We present a
new experimental technique for measuring spectral diffusion based on photon
correlations within a spectral line. Autocorrelation on half of the line and
cross-correlation between the two halves give a quantitative value of the
spectral diffusion time, with a resolution only limited by the correlation
set-up. We have measured spectral diffusion of the photoluminescence of a
single light emitter with a time resolution of 90 ps, exceeding by four orders
of magnitude the best resolution reported to date
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