Inspired by nanoscience and nanoengineering, numerous nanostructured materials developed by multidisciplinary approaches exhibit excellent photoelectronic properties ranging from ultraviolet to terahertz frequencies. As a new class of building block, nanoscale elements in terms of quantum dots, nanowires, and nanolayers can be used for fabricating photodetectors with high performance. Moreover, in conjunction with traditional photodetectors, they exhibit appealing performance for practical applications including high density of integration, high sensitivity, fast response, and multifunction. Therefore, with the perspective of photodetectors constructed by diverse low-dimensional nanostructured materials, recent advances in nanoscale photodetectors are discussed here; meanwhile, challenges and promising future directions in this research field are proposed.
Photoelectric detectors are the central part of modern photodetection systems with numerous commercial and scientific applications. p-Type semiconductor materials play important roles in optoelectronic devices. Photodetectors based on p-type semiconductor materials have attracted a great deal of attention in recent years because of their unique properties. Here, a comprehensive summary of the recent progress mainly on photodetectors based on inorganic p-type semiconductor materials is presented. Various structures, including photoconductors, phototransistors, homojunctions, heterojunctions, p-i-n junctions, and metal-semiconductor junctions of photodetectors based on inorganic p-type semiconductor materials, are discussed and summarized. Perspectives and an outlook, highlighting the promising future directions of this research field, are also given.
Safety, nontoxicity, and durability directly determine the applicability of the essential characteristics of the lithium (Li)‐ion battery. Particularly, for the lithium–sulfur battery, due to the low ignition temperature of sulfur, metal lithium as the anode material, and the use of flammable organic electrolytes, addressing security problems is of increased difficulty. In the past few years, two basic electrolyte systems are studied extensively to solve the notorious safety issues. One system is the conventional organic liquid electrolyte, and the other is the inorganic solid‐state or quasi‐solid‐state composite electrolyte. Here, the recent development of engineered liquid electrolytes and design considerations for solid electrolytes in tackling these safety issues are reviewed to ensure the safety of electrolyte systems between sulfur cathode materials and the lithium‐metal anode. Specifically, strategies for designing and modifying liquid electrolytes including introducing gas evolution, flame, aqueous, and dendrite‐free electrolytes are proposed. Moreover, the considerations involving a high‐performance Li+ conductor, air‐stable Li+ conductors, and stable interface performance between the sulfur cathode and the lithium anode for developing all‐solid‐state electrolytes are discussed. In the end, an outlook for future directions to offer reliable electrolyte systems is presented for the development of commercially viable lithium–sulfur batteries.
A high sensitivity self-powered solar-blind photodetector is successfully constructed based on the polyaniline/MgZnO bilayer. The maximum responsivity of the photodetector is 160 μA W at 250 nm under 0 V bias. The device also exhibits a high on/off ratio of ≈10 under 250 nm illumination at a relatively weak light intensity of 130 μW cm without any power.
A feasible strategy for hybrid photodetector by integrating an array of self-ordered TiO nanotubes (NTs) and selenium is demonstrated to break the compromise between the responsivity and response speed. Novel heterojunction between the TiO NTs and Se in combination with the surface trap states at TiO help regulate the electron transport and facilitate the separation of photogenerated electron-hole pairs under photovoltaic mode (at zero bias), leading to a high responsivity of ≈100 mA W at 620 nm light illumination and the ultrashort rise/decay time (1.4/7.8 ms). The implanting of intrinsic p-type Se into TiO NTs broadens the detection range to UV-visible (280-700 nm) with a large detectivity of over 10 Jones and a high linear dynamic range of over 80 dB. In addition, a maximum photocurrent of ≈10 A is achieved at 450 nm light illumination and an ultrahigh photosensitivity (on/off ratio up to 10 ) under zero bias upon UV and visible light illumination is readily achieved. The concept of employing novel heterojunction geometry holds great potential to pave a new way to realize high performance and energy-efficient optoelectronic devices for practical applications.
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