Conventional phase transitions are well understood in terms of the order parameter, based on the Landau-Ginzburg-Wilson theory. However, unconventional magnetic orders have been observed in clean systems such as MnSi. The unconventional magnetic orders of conduction electrons in the metallic phase has been observed for high-temperature superconductors and heavy fermion compounds. However, these unconventional magnetic orders have been limited to relatively low temperatures as quantum phase transitions. Here high-temperature magnetic short-range order is observed as one of the unconventional magnetic orders at temperatures up to 720 K in a noncentrosymmetric intermetallic antiferromagnet Mn 3 RhSi with a well-ordered lattice. The magnetic Mn ions form a hyperkagome network of cornersharing triangles, where the spins are geometrically frustrated. The spin network is equivalent to that of a spin liquid and non-Fermi-liquid material, β-Mn. Our observation indicates that a metallic phase with magnetic short-range order exists at high temperatures.
The authors previously conducted thermogravimetric analyses on Zircaloy-2 in air. By using the thermogravimetric data, an oxidation model was constructed in this study so that it can be applied for the modeling of cladding degradation in spent fuel pool (SFP) severe accident condition. For its validation, oxidation tests of long cladding tube were conducted, and computational fluid dynamics analyses using the constructed oxidation model were proceeded to simulate the experiments. In the oxidation tests, high temperature thermal gradient along the cladding axis was applied and air flow rates in testing chamber were controlled to simulate hypothetical SFP accidents. The analytical outputs successfully reproduced the growth of oxide film and porous oxide layer on the claddings in oxidation tests, and validity of the oxidation model was proved. Influence of air flow rate for the oxidation behavior was thought negligible in the conditions investigated in this study.
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