In this paper, we are dedicated to exemplifying a two parameter curve fitting method and developing a Matlab-based simulation program to extract the nonlinear refractive index and nonlinear absorption coefficient from closed-aperture Z-scan or R(z) data without the need for performing open-aperture Z-scan measurement. It should be noted, however, that both approaches can only be applicable to a case for which the on-axis phase shift at the focus is small. In this way, we not only determine the nonlinear parameters quickly with reasonable accuracy, as well as save time, efforts and equipment in the process of Z-scan implementation, but also obtain an initial estimate in order to compare with the results of the open-aperture Z-scan measurement when needed.
MoS 2 /TiO 2 heterostructure thin films were fabricated by sol-gel and chemical bath deposition methods. Crystal structure, surface morphology, chemical states of all elements, and optical property of the obtained thin films were characterized by using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis spectroscopy techniques, respectively. Photocatalytic activity of all thin films was evaluated by measuring decomposition rate of methylene blue solution under visible light irradiation. The results indicate that ultrathin MoS 2 film on TiO 2 -glass substrate improves photocatalytic activity of TiO 2 in the visible light due to the efficient absorption of visible photon of MoS 2 few layers and the transfer of electrons from MoS 2 to TiO 2 . All MoS 2 /TiO 2 heterostructure thin films exhibit higher visible light photocatalytic activity than that of pure MoS 2 and TiO 2 counterparts. The best MoS 2 /TiO 2 heterostructure thin film at MoS 2 layer deposition time of 45 minutes can decompose about 60% MB solution after 150 minutes under visible light irradiation. The mechanism of the enhancement for visible-photocatalytic activity of MoS 2 /TiO 2 heterostructure thin film was also discussed.
In this paper, ZnO nanorods were grown by wet chemical method on p-Si (100) substrate to form n-ZnO nanorods/p-Si (100) heterojunction. The optical, electrical, structural properties of n-ZnO nanorods/p-Si(100) heterojunction were analyzed by the photoluminescence (PL) spectroscopy, [Formula: see text]–[Formula: see text] measurement, X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The room temperature PL spectra reveal the good optical property of the heterojunction with strong UV peak at 385[Formula: see text]nm. The ZnO nanorods were vertically well-aligned on p-Si (100) and had an average height of about 1.6[Formula: see text][Formula: see text]m. The n-ZnO nanorods/p-Si (100) heterojunction also exhibits diode-like-rectifying-behavior.
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