a b s t r a c tWe present a computer program and underlying model to calculate the electric susceptibility of a gas, which is essential to predict its absorptive and dispersive properties. Our program focuses on alkali-metal vapours where we use a matrix representation of the atomic Hamiltonian in the completely uncoupled basis in order to calculate transition frequencies and strengths. The program calculates various spectra for a weak-probe laser beam in an atomic medium with an applied axial magnetic field. This allows many optical devices to be designed, such as Faraday rotators/filters, optical isolators and circular polarisation filters. Fitting routines are also provided with the program which allows the user to perform optical metrology by fitting to experimental data. Program summary Program title: ElecSus Catalogue identifier: AEVD_v1_0Program summary URL:

Small numbers of surface-bound molecules are shown to behave as would be expected for optomechanical oscillators placed inside plasmonic nanocavities that support extreme confinement of optical fields. Pulsed Raman scattering reveals superlinear Stokes emission above a threshold, arising from the stimulated vibrational pumping of molecular bonds under pulsed excitation shorter than the phonon decay time, and agreeing with pulsed optomechanical quantum theory. Reaching the parametric instability (equivalent to a phonon laser or "phaser" regime) is, however, hindered by the motion of gold atoms and molecular reconfiguration at phonon occupations approaching unity. We show how this irreversible bond breaking can ultimately limit the exploitation of molecules as quantum-mechanical oscillators, but accesses optically driven chemistry.

Here we report on measurements of the absolute absorption spectra of dense rubidium vapour on the D1 line in the weak-probe regime for temperatures up to 170• C and number densities up to 3 × 10 14 cm −3 . In such vapours, modifications to the homogeneous linewidth of optical transitions arise due to dipole-dipole interactions between identical atoms, in superpositions of the ground and excited states. Absolute absorption spectra were recorded with deviation of 0.1% between experiment and a theory incorporating resonant dipole-dipole interactions. The manifestation of dipole-dipole interactions is a self-broadening contribution to the homogeneous linewidth, which grows linearly with number density of atoms. Analysis of the absolute absorption spectra allow us to ascertain the value of the self-broadening coefficient for the rubidium D1 line: β/2π = (0.69 ± 0.04) × 10 −7 Hz cm 3 , in excellent agreement with the theoretical prediction.

A light, compact optical isolator using an atomic vapor in the hyperfine Paschen-Back regime is presented. Absolute transmission spectra for experiment and theory through an isotopically pure 87 Rb vapor cell show excellent agreement for fields of 0.6 T. We show π/4 rotation for a linearly polarized beam in the vicinity of the D 2 line and achieve an isolation of 30 dB with a transmission > 95 %.

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