The atroposelective synthesis of axially chiral styrenes remains a formidable challenge due to their relatively lower rotational barriers compared to the biaryl atropoisomers. Herein, we describe the construction of axially chiral styrenes through PdII‐catalyzed atroposelective C−H olefination, using a bulky amino amide as a transient chiral auxiliary. Various axially chiral styrenes were produced with good yields and high enantioselectivity (up to 95 % yield and 99 % ee). Carboxylic acid derivatives of the resulting axially chiral styrenes showed superior enantiocontrol over the biaryl counterparts in CoIII‐catalyzed enantioselective C(sp3)−H amidation of thioamide. Mechanistic studies suggest that C−H cleavage is the enantioselectivity‐determining step.

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A large fraction of secondary aerosol particles are liquid−liquid phase-separated with an organic shell and an inorganic core. This has the potential to regulate the hygroscopicity of such particles, with significant implications for their optical properties, reactivity, and lifetime. However, it is unclear how this phase separation affects the hygroscopic growth of the particles. Here, we showed a large variation in hygroscopic growth (e.g., 1.14−1.32 under a relative humidity (RH) of 90%) of particles from the forest and urban atmosphere, which had different average core−shell ratios. For this reason, a controlled laboratory experiment further quantifies the impact of the organic shell on particle growth with different RH values. Laboratory experiments demonstrated that (NH 4 ) 2 SO 4 particles with thicker secondary organic shells have a lower growth factor at an RH below 94%. Organic shells started to deliquesce first (RH > 50%) and the phase changes of sulfate cores from solid to liquid took place at an RH higher than 80% as deliquescence relative humidity of pure (NH 4 ) 2 SO 4 . Our study provides the first direct evidence on an individual particle basis that hygroscopic growth behavior of phase-separated particles is dependent on the thickness of organic shells, highlighting the importance of organic coating in water uptake and possible heterogeneous reactions of the phase-separated particles.

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The cloud base height (CBH) derived from the whole-sky infrared cloud-measuring system (WSIRCMS) and two ceilometers (Vaisala CL31 and CL51) from November 1, 2011, to June 12, 2012, at the Chinese Meteorological Administration (CMA) Beijing Observatory Station are analysed. Significant differences can be found by comparing the measurements of different instruments. More exactly, the cloud occurrence retrieved from CL31 is 3.8% higher than that from CL51, while WSIRCMS data shows 3.6% higher than ceilometers. More than 75.5% of the two ceilometers' differences are within ±200 m and about 89.5% within ±500 m, while only 30.7% of the differences between WSIRCMS and ceilometers are within ±500 m and about 55.2% within ±1000 m. These differences may be caused by the measurement principles and CBH retrieval algorithm. A combination of a laser ceilometer and an infrared cloud instrument is recommended to improve the capability for determining cloud occurrence and retrieving CBHs.