Wearing
face masks has been widely recommended to contain respiratory
virus diseases, yet the improper use of masks poses a threat of jeopardizing
the protection effect. We here identified the bacteria viability on
common face masks and found that the majority of bacteria (90%) remain
alive after 8 h. Using laser-induced graphene (LIG), the inhibition
rate improves to ∼81%. Combined with the photothermal effect,
99.998% bacterial killing efficiency could be attained within 10 min.
For aerosolized bacteria, LIG also showed superior antibacterial capacity.
The LIG can be converted from a diversity of carbon precursors including
biomaterials, which eases the supply stress and environmental pressure
amid an outbreak. In addition, self-reporting of mask conditions is
feasible using the moisture-induced electricity from gradient graphene.
Our results improve the safe use of masks and benefit the environment.
Molecular complexes with inexpensive transition‐metal centers have drawn extensive attention, as they show a high selectivity in the electrochemical conversion of CO2 to CO. In this work, we propose a new strategy to covalently graft cobalt porphyrin onto the surface of a carbon nanotube by a substitution reaction at the metal center. Material characterization and electrochemical studies reveal that the porphyrin molecules are well dispersed at a high loading of 10 wt. %. As a result, the turnover frequency for CO formation is improved by a factor of three compared to traditional physically‐mixed catalysts with the same cobalt content. This leads to an outstanding overall current density of 25.1 mA cm−2 and a Faradaic efficiency of 98.3 % at 490 mV overpotential with excellent long‐term stability. This work provides an effective pathway for the improvement of the performance of electrocatalysts that could inspire rational design of molecular catalysts in the future.
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