In this research, we studied the formation of laser-induced periodic surface structures on the stainless steel surface using femtosecond laser pulses. A 780 nm wavelength femtosecond laser, through a 0.2 mm pinhole aperture for truncating fluence distribution, was focused onto the stainless steel surface. Under different experimental condition, low-spatial-frequency laser-induced periodic surface structures with a period of 526 nm and high-spatial-frequency laser-induced periodic surface structures with a period of 310 nm were obtained. The mechanism of the formation of laser-induced periodic surface structures on the stainless steel surface is discussed.
When
studying surface nanobubbles on film-coated substrates, a
class of bubble-like domains called blisters are probably forming
at the solid–liquid interface together with nanobubbles. This
may easily lead to a misunderstanding of the characteristics and applications
of surface nanobubbles and thus continue to cause problems within
the nanobubble community. Therefore, how to distinguish surface nanobubbles
from blisters is a problem. Herein, the morphology and properties
of blisters are investigated on both smooth and nanopitted polystyrene
(PS) films in degassed water. The morphology and contact angle of
blisters are similar to those of surface nanobubbles. However, blisters
were observed to be punctured under the tip–blister interaction
and be torn broken by an atomic force microscope tip during the process
of scanning. At the same time, nanopits on the surface of blisters
that formed on a pitted PS film can be seen clearly. These provide
direct and visual evidence for distinguishing blisters from surface
nanobubbles. In addition, surface nanobubbles and blisters on smooth
and pitted PS films in air-equilibrated water are studied. No punctured
surface nanobubble was observed, and the force curves obtained on
surface nanobubbles and the change in height of blisters and surface
nanobubbles under a large scanning force show that surface nanobubbles
are much softer than blisters.
Trapped nanobubbles are gas domains trapped at nanopits on the solid−liquid interface. This is different from surface nanobubbles that usually form at the smooth surface. Herein, both trapped nanobubbles and surface nanobubbles formed on the nanopitted polystyrene film were studied by a spontaneous formation method and a temperature difference method. Trapped nanobubbles behave more flexibly than surface nanobubbles under different scanning loads. The nanopits under trapped nanobubbles appear after being subjected to large force scanning, and both trapped nanobubbles and surface nanobubbles can recover after reducing the scan load. The contact angles of the two kinds of nanobubbles were calculated and were found to be approximately constant. Configurations of trapped nanobubbles including under the pit mouth, protruding out but pinning at the pit mouth, and protruding out and extending around the pit mouth were experimentally observed. Gas oversaturation in the liquid after replacing the low-temperature water with high-temperature water was evaluated and was found to be a key factor for nanobubble formation and led to trapped nanobubbles protruding out and extending. Our study should be helpful in understanding the formation mechanism and properties of trapped nanobubbles and surface nanobubbles, and it will also be useful for further research on the control of nanobubble distribution.
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