A pectin/chitosan matrix-loaded curcumin film (PCCF) with a deep eutectic solvent (DES) as the solvent and plasticizer was prepared in this study. Different quantities of curcumin (identified as PCCF-0, PCCF-1, PCCF-2. PCCF-3) were loaded on the pectin/chitosan film in order to evaluate their effects on the film properties. Results showed that curcumin could interact with the pectin/chitosan matrix and form a complex three-dimensional network structure. PCCF could promote the thickness, tensile strength, thermal properties, antioxidant and antiseptic capacities, but deteriorate the light transmission and elongation at the same time. The addition of curcumin would change the color of the film, without significantly affecting the moisture content. The tensile strength of PCCF-3 reached the maximum value of 3.75 MPa, while the elongation decreased to 10%. Meanwhile, the water-resistance properties of PCCF-3 were significantly promoted by 8.6% compared with that of PCCF-0. Furthermore, PCCF showed remarkable sustained antioxidant activities in a dose-dependent manner. PCCF-3 could inhibit DPPH and ABTS free radicals by 58.66% and 29.07%, respectively. It also showed antiseptic capacity on fresh pork during storage. Therefore, curcumin addition could improve the barrier, mechanical, antioxidant and antiseptic properties of the polysaccharide-based film and PCCF has the potential to be used as a new kind of food packaging material in the food industry.
Additive manufacturing of arbitrary shapes and unique architecture provides remarkable flexibility and simplicity for the preparation of highly complex conformal electronics. This drives up demand for electronic materials with excellent process ability and functionality from one‐step molding of microminiature to large‐scale devices. Herein, a novel method is introduced for fabricating high‐performance barium titanate (BaTiO3)‐polydimethylsiloxane composites based on three‐dimensional (3D)‐printing‐ordered structure of a metamaterial skeleton. When subjected to external mechanical stress, the metamaterial structure facilitates effective stress transfer, resulting in a significantly improved voltage output. In comparison to traditional low‐dimensional ceramic polymer composites, metamaterial‐structured BaTiO3 composites exhibit excellent electromechanical energy conversion properties, thereby enabling tactile imitation applications and mechanical energy harvesting. This study proposes a novel strategy for biological signal identification and implantable self‐powered electronic applications.
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