We demonstrate an effective method for depositing smooth silver (Ag) films on SiO(2)/Si(100) substrates using a thin seed layer of evaporated germanium (Ge). The deposited Ag films exhibit smaller root-mean-square surface roughness, narrower peak-to-valley surface topological height distribution, smaller grain-size distribution, and smaller sheet resistance in comparison to those of Ag films directly deposited on SiO(2)/Si(100) substrates. Optically thin ( approximately 10-20 nm) Ag films deposited with approximately 1-2 nm Ge nucleation layers show more than an order of magnitude improvement in the surface roughness. The presence of the thin layer of Ge changes the growth kinetics (nucleation and evolution) of the electron-beam-evaporated Ag, leading to Ag films with smooth surface morphology and high electrical conductivity. The demonstrated Ag thin films are very promising for large-scale applications as molecular anchors, optical metamaterials, plasmonic devices, and several areas of nanophotonics.
The ability to grow dissimilar materials with large lattice mismatches on a single substrate removes the integration related constraints of incorporating photonics with electronics. We review our recent nanoheteroepitaxy efforts on the epitaxial growth of bridged InP NWs between two vertical, (111)-oriented Si surfaces by forming connections during the NW growth facilitating their direct electrical probing via Si electrodes and a new method of synthesizing III-V NWs on a non-single crystalline surface that directly relaxes any lattice matching conditions. The currentvoltage behavior with temperature and the resulting photoenhanced thermal failure is also discussed.
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