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Film forming, stable hybrid latexes made of methyl metacrylate (MMA), butyl acrylate (BA) and 2-hydroxyethyl methacrylate (HEMA) copolymer reinforced with modified multiwalled carbon nanotubes (MWCNTs) were synthesized by in situ miniemulsion polymerization. The MWCNTs were pretreated by an air sonication process and stabilized by polyvinylpyrrolidone. The presence of the MWCNTs had no significant effect on the polymerization kinetics, but strongly affected the polymer characteristics (T g and insoluble polymer fraction). The performance of the in situ composites was compared with that of the neat polymer dispersion as well as with those of the polymer/MWCNT physical blends. The in situ composites showed the presence of an additional phase likely due to the strong interaction between the polymer and MWNCTs (including grafting) that reduced the mobility of the polymer chains. As a result, a substantial increase of both the storage and the loss moduli was achieved. At 60 °C, which is above the main transition region of the polymer, the in situ composites maintained the reinforcement, whereas the blends behaved as a liquid-like material. This suggests the formation of a 3D network, in good agreement with the high content of insoluble polymer in the in situ composites.

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The thermal performance of closed-cell foams as an insulation device depends on the thermal conductivity. In these systems, the heat transfer mode associated with the convective contribution is generally ignored, and studies are based on the thermo-physical properties that emerge from the conductive contribution, while others include a term for radiative transport. The criterion found in the literature for disregarding convective heat flux is the cell diameter; however, the cell size for which convection is effectively suppressed has not been clearly disclosed, and it is variously quoted in the range 3–10 mm. In practice, changes in thermal conductivity are also attributed to the convection heat transfer mode; hence, natural convection in porous materials is worthy of research. This work extends the field of study of conjugate heat transfer (convection and conduction) in cellular materials using microstructure-based finite element analysis. For air-based insulating materials, the criteria to consider natural convection (Ra=103) is met by cavities with sizes of 9.06 mm; however, convection is developed into several cavities despite their sizes being lower than 9.06 mm, hence, the average pore size that can effectively suppress the convective heat transfer is 6.0 mm. The amount of heat transported by convection is about 20% of the heat transported by conduction within the foam in a Ra=103, which, in turn, produces an increasing average of the conductivity of about 4.5%, with respect to a constant value.

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