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Full quantum calculations are performed to determine the spectral broadening of the rubidium D1 and D2 lines induced by collisions with helium perturbers. The potential curves of the low-lying RbHe molecular states, as well as the corresponding transition dipole moments, are generated theoretically with ab initio methods based on SA-CASSCF-MRCI calculations, including the spin–orbit effects. The absorption and emission coefficients at wavelengths lying between 650 and and temperatures ranging from 100 to 3000 K are determined. The absorption profile reveals it is dominated by the free–free transitions, whereas the emission spectral shape arises from the free–free and bound–free transitions. The resulting red- and blue-wing profiles are compared with previous experimental and theoretical works.

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Polymer materials - mainly epoxy resins - are widely used in microelectronics packaging. They are established in printed circuit board manufacturing, for adhesives as die attach glues or for encapsulants as molding compounds, glob tops or underfill materials. Low cost and mass production capabilities are the main advantages of these materials. But like all polymers they can not provide a hermetical sealing due to their permeability properties. The susceptibility to water diffusion through the polymer and along the interfaces is a drawback for polymer materials in general. Water inside a microelectronic package might lead to softening of the material and to a decreasing adhesive strength and resulting delaminations close to solder bumps or wire bonds reducing package reliability by decreasing the package structural integrity. During package reflow, the incorporated humidity might lead to popcorning, i.e. abrupt evaporation of humidity during reflow soldering, is one major problem during plastic package assembly. The introduction of high temperature lead- free soldering processes has even increased this issue. Therefore, plastic packaging materials with enhanced humidity resistance would increase package reliability during assembly and lifetime without cost increase and with no changes in processing. The incorporation of nano-particles into plastic packaging materials is discussed as one potential solution for improved humidity resistance as it is a rather low effort approach to material modification opposed to chemical modification of the matrix. To evaluate the potential of such additives concerning moisture resistance the effect of nano-particles mixed with a microelectronic grade epoxy resin is studied. From the large variety of fillers available this work mainly focuses on three different types: nano-sized silica, modified bentonite and zeolites. Working principles of these particles range from large surface impact of nano-particles, barrier functionality due to - stacked layer formation and molecular catcher function. Formulations with different particle concentrations and surface modifications are characterized regarding their influence on humidity diffusion, absorption and desorption behavior as well as their influence on other material properties as reaction kinetics, viscosity and thermo- mechanical properties. Additionally the combination of nano- and standard micro-particles needed for thermo-mechanical adjustment of the polymer properties is studied. Experimental work is accompanied by simulations, in order to provide further qualitative understanding on effects of particle form, size and surface properties. In summary this paper describes the potential of different nano-particles as additives for plastic packaging materials for enhanced humidity resistance/barrier enhancement within microelectronic packages. This topic is gaining increased importance when considering the trend towards system in package, where a multitude of components is encapsulated to form one SiP that incorporates a large number of...

Metal degradation has recently received increased attention as a failure mechanism in power devices under active cycling conditions, i.e. under repeated pulsed voltage/current loads [1, 2]. Both electro-thermal and thermo-mechanical simulation are indispensable for understanding this mechanisms. The paper presents experimental and simulation data for a dedicated test structure. A suitable lifetime model has to go beyond a simple Coffin-Manson type model to capture the essential influencing parameters