The absorption spectrum of the explosive 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) has been measured using a conventional Fourier transform infrared spectroscopy and by terahertz pulsed spectroscopy. Seven absorption features in the spectral range of 5–120cm−1 have been observed and identified as the fingerprint of RDX. Furthermore, the spatial distribution of individual chemical substances including RDX, has been mapped out using reflection terahertz spectroscopic imaging in combination with component spatial pattern analysis. This is the terahertz spectroscopy and chemical mapping of explosives obtained using reflection terahertz measurement, and represents a significant advance toward developing a terahertz pulsed imaging system for security screening of explosives.

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The relatively short wavelength of mm-wave and THz radiation coupled with good transmission through many dielectric materials allows images to be formed of concealed objects. This chapter gives an overview of the detectors, their associated circuitry, and system developments over the past 10 years, focussing on personnel security screening. We will discuss the phenomenology of imaging at these wavelengths, introduce the reader to the basic architectures being used and developed for image forming instruments, show examples of systems, and also discuss the feasibility of spectroscopic THz imaging for security screening applications.

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