M. Hahn scite author profile

M. Hahn

5Publications

38Citation Statements Received

2Citation Statements Given

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Ruhr University Bochum

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Hydroxylamido(1‐)‐O,N‐Komplexe des Molybdäns(VI) mit terminalen Oxo‐, Sulfido‐ und Selenido‐Liganden Die Kristallstrukturen von [MoO₂(C₅H₁₀NO)₂] und von [MoS₂(C₅H₁₀NO)₂]

Wieghardt¹,

Hahn²,

Weiß³

et al. 1982

Zeitschrift anorg allge chemie

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Die Neutralkomplexe cis‐Dioxo‐bis(hydroxylamido(1‐)‐O, N)molybdän(VI) mit O,N‐koordinierten, N,N‐substituierten Hydroxylamin‐Liganden reagieren mit H2S in Toluol unter Substitution einer oder beider terminaler Oxo‐Gruppen zu cis‐Oxosulfido‐ bzw. cis‐Disulfido‐bis(hydroxylamido(1‐)‐O, N)molybdän(VI)‐Komplexen; mit H2Se entstehen die entsprechenden cis‐Oxoselenido‐Komplexe. Die Kristallstrukturen der Titelverbindungen mit Piperidin‐N‐oxid als Ligand werden beschrieben: Der cis‐Disulfido‐Komplex kristallisiert tetragonal in der Raumgruppe D 2d11—I 4 2 m mit vier Formeleinheiten i. d. Elementarzelle; die analoge cis‐Dioxo‐Verbindung kristallisiert orthorhombisch (D 24—P212121) mit 4 FE i. d. EZ. Die 1H—NMR‐Spektren sowie die Lichtabsorptionsspektren werden mitgeteilt.

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Molybdenum-95 NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum(VI)

Minelli¹,

Enemark²,

Wieghardt³

et al. 1983

Inorg. Chem.

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Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O

Weighardt¹,

Hahn²,

Swiridoff³

et al. 1984

Inorg. Chem.

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Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+)

Hahn¹,

Wieghardt²

1984

Inorg. Chem.

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The reaction of cis-dioxo-bis(N-methylhydroxylamido(1-)-(O,N))molybdenum(VI) with alkyl-isocyanates. Crystal structure of cis-dioxo-bis(N-tert.butyl-N′-methyl-N′-oxo-ureato(1-)-(O,O′))molybdenum(VI)

Hahn

Wieghardt

Swiridoff

et al. 1984

Inorganica Chimica Acta

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M. Hahn

Hydroxylamido(1‐)‐O,N‐Komplexe des Molybdäns(VI) mit terminalen Oxo‐, Sulfido‐ und Selenido‐Liganden Die Kristallstrukturen von [MoO₂(C₅H₁₀NO)₂] und von [MoS₂(C₅H₁₀NO)₂]

Molybdenum-95 NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum(VI)

Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O

Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+)

The reaction of cis-dioxo-bis(N-methylhydroxylamido(1-)-(O,N))molybdenum(VI) with alkyl-isocyanates. Crystal structure of cis-dioxo-bis(N-tert.butyl-N′-methyl-N′-oxo-ureato(1-)-(O,O′))molybdenum(VI)

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M. Hahn

Hydroxylamido(1‐)‐O,N‐Komplexe des Molybdäns(VI) mit terminalen Oxo‐, Sulfido‐ und Selenido‐Liganden Die Kristallstrukturen von [MoO2(C5H10NO)2] und von [MoS2(C5H10NO)2]

Molybdenum-95 NMR studies of dioxo, oxo-sulfido, oxo-selenido, and disulfido complexes of molybdenum(VI)

Preparation and characterization of binuclear (1,4,7-triazacyclononane)molybdenum(III) complexes. Crystal structures of [MoIII2(.mu.-OH)2Cl2(C6H15N3)2]I2 and [MoIII2(.mu.-OH)2(.mu.-O2CCH3)(C6H15N3)2]I3.H2O

Kinetics and mechanism of the oxidation of bis(.mu.-hydroxo)bis[aqua(1,4,7-triazacyclononane)molybdenum(III)](4+) by perchlorate. Acid-base-catalyzed trans .fwdarw. cis isomerization of bis(.mu.-oxo)-trans-dioxobis[(1,4,7-triazacyclononane)molybdenum(V)](2+)

The reaction of cis-dioxo-bis(N-methylhydroxylamido(1-)-(O,N))molybdenum(VI) with alkyl-isocyanates. Crystal structure of cis-dioxo-bis(N-tert.butyl-N′-methyl-N′-oxo-ureato(1-)-(O,O′))molybdenum(VI)

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Hydroxylamido(1‐)‐O,N‐Komplexe des Molybdäns(VI) mit terminalen Oxo‐, Sulfido‐ und Selenido‐Liganden Die Kristallstrukturen von [MoO₂(C₅H₁₀NO)₂] und von [MoS₂(C₅H₁₀NO)₂]