The bioactivity and the corrosion protection for a novel nano-grained Ti-20Nb-13Zr at % alloy were examined in a simulated body fluid (SBF). The effect of the SPS’s temperature on the corrosion performance was investigated. The phases and microstructural details of the developed alloy were analyzed by XRD (X-ray Diffraction), SEM (Scanning Electron Microscopy), and TEM (Transmission Electron Microscope). The electrochemical study was investigated using linear potentiodynamic polarization and electrochemical impedance spectroscopy in a SBF, and the bioactivity was examined by immersing the developed alloy in a SBF for 3, 7, and 14 days. The morphology of the depositions after immersion was examined using SEM. Alloy surface analysis after immersion in the SBF was characterized by XPS (X-ray Photoelectron Spectroscopy). The results of the bioactivity test in SBF revealed the growth of a hydroxyapatite layer on the surface of the alloy. The analysis of XPS showed the formation of protective oxides of TiO2, Ti2O3, ZrO2, Nb2O5, and a Ca3(PO4)2 compound (precursor of hydroxyapatite) deposited on the alloy surface, indicating that the presented alloy can stimulate bone formation. The corrosion resistance increased by increasing the sintering temperature and the highest corrosion resistance was obtained at 1200 °C. The improved corrosion protection was found to be related to the alloy densification. The bioactivity and the corrosion resistance of the developed nanostructured alloy in a SBF renders the nanostructured Ti-20Nb-13Zr alloy a promising candidate as an implant material.

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In the present study, we have synthesized two novel corrosion inhibitors BP-1 and BP-2 and evaluated their corrosion inhibition property on mild steel (MS) in acid solution through weight loss and electrochemical corrosion techniques. The corrosion test results reveal that both compounds inhibit corrosion by an adsorption mechanism and display inhibition efficiency more than 95% at a low concentration of 1.72 × 10 –4 M. From the surface analysis of the protective film on MS, it was corroborated that adsorption of inhibitor molecules occurred on the MS surface through chemisorption, which further suppresses the corrosion rate. Density functional theory simulated data helps correlate the experimental trend with the theoretical study.

Metal matrix composites possess some glamorous properties like light weight, low density ,high strength-to-density ratio, formable to complex shape, lower manufacturing cost and are used more in commercial, industrial, marine, naval based industrial and are extensively used in automobiles and aerospace like empennage, wings, fuselage in fighter aircraft, bomber, transport, general aviation, rotary aircraft etc. Many researches are done on micro structural metals matrix composites and they result shows that composite of micro structural having good mechanical properties. Instead of using micro structural nanoparticles are used for better mechanical properties and better applications in aeronautical field. The present study is an attempt to prepare and analysis of mechanical properties of Aluminium 6061 reinforcement with TiB2nanoparticles using liquid metallurgy. By the use of ball milling process the TiB2micro particles are converted in to nanoparticles and reinforced with Aluminium 6061 in stir casting process. The addition level of reinforcement is being varied from 0-15wt% in step of 4 wt%.Test carried out on the fabricated composite included scanning electron microscopy, XRD, EDAX analysis, and Thermal analysis.

Ti alloys have been widely used for biomedical applications.The generated wear debris due to its low wear resistance lead to inflammations and reduce the lifetime of the implant. So, the coating has been used to improve corrosion and wear resistance. In the present work, we report the assessments of TiN coating deposited by CA-PVD on Ti6Al4V alloy for dental applications. The deposited coating was characterized by XRD and SEM. Mechanical properties were assessed using micorindentation. The in vitro corrosion properties was investigated using PDP and EIS in artificial saliva. The wear rate was characterized using the linear reciprocating tribometer. The results showed that a TiN layer with 1.8 µm thickness was deposited with a hardness of 24.9±8.123 GPa and a Modulus of elasticity of 244.7±14.8 GPa. The corrosion study revealed enhancement in the corrosion performance of the coated sample in artificial saliva. The wear rate of the coated samples was also enhanced for the coated sample. The improved surface hardness, corrosion and wear characteristics of the TiN coating suggests that TiN coating would be a potential candidate for dental applications.