Alternating current (AC) electrophoretic deposition (EPD) was used to produce multifunctional composite coatings combining bioactive glass (BG) particles and chitosan. BG particles of two different sizes were used, i.e., 2 μm and 20–80 nm in average diameter. The parameter optimization and characterization of the coatings was conducted by visual inspection and by adhesion strength tests. The optimized coatings were investigated in terms of their hydroxyapatite (HA) forming ability in simulated body fluid (SBF) for up to 21 days. Fourier transform infrared (FTIR) spectroscopy results showed the successful HA formation on the coatings after 21 days. The first investigations were conducted on planar stainless steel sheets. In addition, scaffolds made from a TiAl4V6 alloy were considered to show the feasibility of coating of three dimensional structures by EPD. Because both BG and chitosan are antibacterial materials, the antibacterial properties of the as-produced coatings were investigated using E. coli bacteria cells. It was shown that the BG particle size has a strong influence on the antibacterial properties of the coatings.
Water-based processing of electrodes is associated with an enhanced environmental footprint for lithium-ion battery (LIB) production in conjunction with reduced costs. This trend is accompanied by an increasing demand for electrode dispersion processing in inkjet printing. However, most of the dispersion components show a low inherent dispersibility with poor stability in aqueous formulations. This is particularly important when it comes to qualifying electrode dispersions for use in inkjet printing, since the effect of agglomeration and sedimentation effects must be effectively prevented. Therefore, additives are needed to improve the dispersive behavior. This paper analyzes the suitability of dispersants for organic electrode components, in particular graphite and carbon black. An empirical approach was devised on the basis of comprehensive theoretical considerations. Empirical investigations revealed that the utilization of polyvinylpyrrolidone (PVP) favored the enhanced stabilization of graphite nanoparticles. The addition of Triton X-100 (TX-100) resulted in an improved stabilization of carbon black. Based on these empirical studies, a methodology was derived, which supports the application of suitable dispersants in printable dispersions.
In binder jetting (BJ), an ink is inserted layerwise into a powder bed to selectively bond the particles in the cross-section of a part. By predicting the penetration depth of the ink, the ideal layer thickness for BJ can be set. Each layer should be penetrated with ink. Insufficient penetration will result in a poor layer bond and a low strength of the part; over-penetration will impede a dimensionally accurate production, as the ink will leak from the sides of the part and unintentionally solidify the powder in these areas. The Washburn equation has been used for the calculation of the penetration depth in various fields, such as hydrology or with loose powders. However, a transfer to the BJ process is difficult due to the preferably compact powder bed and the fine particles. In more compact powder beds, the small radii with their greater capillary pressure and their distribution in the layer have a high influence on the penetration depth. This work shows an adaptation of the Washburn equation for powder beds in BJ and a new approach to determine the effective pore radius for calculating the penetration depth. A weighted pore radius was introduced, which accounts for the spatial distribution of the pores in the powder bed and the acting capillary pressure. The validation was performed with two different powders by experimentally simulating the BJ process through the infiltration of a drop into a powder bed. The weighted radius was used in the Washburn equation to calculate the penetration depth. The results were compared with those models from the literature and experimental data, and a good agreement between the calculation and the experiment was found.
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