Flour from old varieties are usually considered very weak flours, and thus difficult to use in breadmaking especially when processed as Italian “Tipo 2” flour. Hence, the aim of our study was to understand if agronomic treatments can be used to improve flour processability and the quality of three old wheat varieties. An experimental strip-plot scheme was used: three old wheat varieties (Andriolo, Sieve, Verna), two seeding densities, three levels of nitrogen fertilization (N35, N80, and N135), and two levels of foliar sulfur fertilization. Analyzed parameters related to kernel composition, dough rheology and bread quality. Sulfur and nitrogen treatments significantly affected protein composition and dough alveograph strength, which increased by about 34% with nitrogen fertilization, and by about 14% with the sulfur treatment. However, only nitrogen fertilization affected bread characteristics. Crumb density significantly decreased from N35 to N135, while springiness and cohesiveness increased. On the other hand, sulfur did not improve breads. This highlight the importance of performing breadmaking tests in addition to the rheological determinations. The poor technological performance of old wheat flours can be improved with agronomical treatments designed to obtain higher-quality bread.
Although the use of pesticides has highlighted obvious advantages on agricultural yields, intensive and widespread pesticide use raises serious environmental and health concerns. In particular, organophosphate pesticides represent >40% of the totality used in the field of agriculture, and developing countries face the issue of agricultural poisoning, also due to scarce monitoring programs. In this work, a decentralized, miniaturized, sustainable, and portable paper-based electrochemical biosensor for the quantification of organophosphorus pesticides' level has been realized. The proposed approach highlights the use of a very common paper-based substrate, namely, office paper. Office paper offers several advantages due to its nature: it allows one to print conductive strips for electrochemical connection, loading bio-hybrid nanosized probes (Prussian blue, carbon black, and butyrylcholinesterase), evaluating pesticides and reducing waste disposal compared to plastic-based strips. The portable system has been characterized by a low detection limit of 1.3 ng/mL, and accordingly to total discovered pesticide contents in EU agricultural soils, up to ca. 3 μg/mL, it can offer a valuable tool for fast monitoring. To demonstrate its effectiveness, soil and fruit vegetables have been used to perform in situ quantification. Good recovery percentages between 90 and 110% have been achieved in different matrices, highlighting to be suitable for field measurements, and a good correlation has been obtained in comparison with LC−MS analysis.
SUMMARYClimate represents one of the main inputs necessary for plants to complete their vegetative–productive cycle, having a direct effect on the onset and duration of phenological stages and development of crops. Equally important are its indirect effects, affecting field operations such as the application of fertilizer, pruning and crop protection, finally determining the yield.In the present study, phenological stages of the Sangiovese grapevine for the production of Nobile di Montepulciano wine were analysed and related to historical series of meteorological information (since 1970 in Tuscany, Italy). Weather conditions were described through large-scale meteorological information; in particular geopotential height at the 500 hPa level (500 hPa GPH) and North Atlantic Oscillation (NAO) index were considered. All data were provided by the National Oceanic and Atmospheric Administration-Cooperative Institute for Research in Environmental Sciences (NOAA-CIRES) Climate Diagnostics Center, Boulder, Colorado, USA, available from the NOAA-CIRES website (http://www.cdc.noaa.gov/) and processed by the National Center for Environmental Prediction/National Center for Atmospheric Research (NCEP/NCAR) Reanalysis Project. Conventional meteorological data, such as air temperature and cumulated rainfall, from ground weather stations were also used.The effects of meteorological parameters on crop phenology (bud-break, flowering and harvest time) were investigated by means of regression analysis, while teleconnections between phenological data and large-scale meteo-climatological data were analysed through correlation maps created using the interactive plotting and analysis link from the NOAA-CIRES website (http://www.cdc.noaa.gov). All correlations were calculated on a monthly to a multi-monthly basis, and also in relation to the different physiological stages of the crop, from 1970 to 2006.The climate change and variability impact on the crop was investigated by trend analysis of meteorological information and its effect on the onset of grapevine phenological stages.The results demonstrated that large-scale meteorological information has a significant effect on the onset of the phenological stages of grapevine. In particular, winter NAO was negatively correlated with bud-break and flowering dates, while GPH of February–March, March–May and May–September were negatively correlated with bud-break, flowering and harvest dates, respectively. The trend analysis demonstrated that the change and variability of climate, due to global warming, directly affects the development of grapevine leading to an anticipation of all considered phenophases.
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