No abstract

Different studies in the literature indicate the effectiveness of CNTs as reinforcing materials in cement–matrix composites due to their high mechanical strength. Nevertheless, their incorporation into cement presents some difficulties due to their tendency to agglomerate, yielding a non-homogeneous dispersion in the paste mix that results in a poor cement–CNTs interaction. This makes the surface modification of the CNTs by introducing functional groups on the surface necessary. In this study, three different treatments for incorporating polar oxygen functional groups onto the surface of carbon nanotubes have been carried out, with the objective of evaluating the influence of the type and oxidation degree on the mechanical and electrical properties and in strain-sensing function of cement pastes containing CNTs. One treatment is in liquid phase (surface oxidation with HNO3/H2SO4), the second is in gas phase (O3 treatment at 25 and 160 °C), and a third is a combination of gas-phase O3 treatment plus NaOH liquid phase. The electrical conductivity of cement pastes increased with O3- and O3-NaOH-treated CNTs with respect to non-treated ones. Furthermore, the oxygen functionalization treatments clearly improve the strain sensing performance of the CNT-cement pastes, particularly in terms of the accuracy of the linear correlation between the resistance and the stress, as well as the increase in the gage factor from 28 to 65. Additionally, the incorporation of either non-functionalized or functionalized CNTs did not produce any significant modification of the mechanical properties of CNTs. Therefore, the functionalization of CNTs favours the de-agglomeration of CNTs in the cement matrix and consequently, the electrical conductivity, without affecting the mechanical behaviour.

This paper provides a methodology for the prediction of fracture loads in additively manufactured ABS material containing U-notches. The approach is based on the Average Strain Energy Density (ASED) criterion, which assumes that the material being analysed develops fully linear-elastic behaviour. Thus, in those cases where the material has a certain (non-negligible) amount of non-linear behaviour, the ASED criterion needs to be corrected. In this sense, in this paper, the ASED criterion is also combined with the Equivalent Material Concept (EMC) and the Fictitious Material Concept (FMC), both being corrections in which the non-linear real material is substituted by a linear equivalent or fictitious material, respectively. The resulting methodologies have been applied to additively manufactured ABS U-notched single-edge-notched bending (SENB) specimens combining five different notch radii (0, 0.25, 0.5, 1 and 2 mm) and three different raster orientations (0/90, 45/−45 and 30/−60). The results obtained demonstrate that both the ASED-EMC and the ASED-FMC combined criteria provide more accurate predictions than those obtained directly through the ASED criterion, with the ASED-EMC criterion generally providing safe more accurate predictions, with an average deviation from the experimental fracture loads between +1.0% (predicted loads higher than experimental loads) and −7.6% (predicted loads lower than experimental loads).

No abstract

No abstract