Patients with olfactory dysfunction showed decreased taste sensitivity which suggested an interaction between the chemical senses taste, trigeminal function, and olfaction. This provides the basis for including both smell and taste psychophysical assessment in clinical practices. In addition, patients with taste loss appeared to suffer most from chemosensory dysfunction.
Noble-metal aerogels are emerging functional porous materials
that
have been applied in diverse fields. Among them, gold (Au) aerogels
have displayed grand potentials in a wide range of catalytic processes.
However, current fabrication methods fall short in obtaining Au gels
with small ligament sizes and controlled surface valence states, which
hinder the study of the underlying catalytic mechanisms. Here, a new
approach of producing Au aerogels is reported. Via a two-phase ligand
exchange, the long-chain ligands (oleylamine) of the as-prepared Au
nanoparticles were replaced by short sulfide ions and subsequently
self-assembled into three-dimensional gels. As a result, Au aerogels
with small ligament sizes (ca. 3–4 nm) and tunable surface
valence states are acquired. Taking the application for peroxidase
mimics as an example, by correlating the surface valence with the
catalytic properties, Au(I) is found to be the active site for H2O2 and substrate-binding site for 3,3′,5,5′-tetramethylbenzidine,
paving a new avenue for on-target devising Au-based catalysts.
As there is a great demand of 2D metal networks, especially out of gold for a plethora of applications we show a universal synthetic method via phase boundary gelation which allows the fabrication of networks displaying areas of up to 2 cm
2
. They are transferred to many different substrates: glass, glassy carbon, silicon, or polymers such as PDMS. In addition to the standardly used web thickness, the networks are parametrized by their fractal dimension. By variation of experimental conditions, we produced web thicknesses between 4.1 nm and 14.7 nm and fractal dimensions in the span of 1.56 to 1.76 which allows to tailor the structures to fit for various applications. Furthermore, the morphology can be tailored by stacking sheets of the networks. For each different metal network, we determined its optical transmission and sheet resistance. The obtained values of up to 97 % transparency and sheet resistances as low as 55.9 Ω/sq highlight the great potential of the obtained materials.
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