In this study, yellow thermally activated delayed fluorescence (TADF) emitter PTZ-SA has been designed and synthesized by incorporating phenothiazine as donor and benzothiadiazine-1,1-dioxide as an acceptor. The molecule is also screened for aggregation induced emission in THF/Water system. PTZ-SA shows exceptionally high glass transition temperature (T g ) of 188 °C which clearly highlights good thermal stability of the material. The energy gap (ΔE ST ) between singlet (S1) and triplet (T1) excitons is sufficiently small (0.08 eV) for the reverse intersystem crossing. Yellow electroluminescence peak is observed at 568 nm with Commission Internationale de L'Eclairage coordinates of (0.44, 0.50). The external quantum efficiency of 4.2 % from PTZ-SA is achieved in yellow emitting OLED with turn on voltage of 5.1 V. Moreover, sufficiently high triplet energy of 2.5 eV and good film forming ability of PTZ-SA, encouraged us to study its electro-phosphorescent properties. Nevertheless, the red phosphorescent OLED device incorporating PTZ-SA dopped with a red emitter Ir(piq) 2 acac exhibited maximum external quantum efficiency, power efficiency and luminescence efficiency of 8.1 %, 7.2 lm W À 1 and 5.1 cd A À 1 , respectively.
We propose a new flexible transparent composite electrode that uses an ultra-thin silver-chromium (AgCr) alloy film to increase the conductivity of a Mo-doped GaZnO (MGZO) thin film and to maintain...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.