In
this work, the sensitive detection of hydrogen sulfide (H2S) was realized at low cost and high efficiency through the application
of silver–gold core–shell nanoprism (Ag@Au-np) combined
with headspace single-drop microextraction (HS-SDME). After SDME,
smartphone nanocolorimetry (SNC), with the aid of a smartphone camera
and color picker software, was used to detect and quantify the H2S. The method took advantage of the inhibition of the ultraviolet–visible
(UV–vis) signal caused by H2S etching of the Ag@Au-np
preadded to the SDME solvent to measure the H2S concentration.
The coating of the gold layer not only ensured the high stability
of the nanomaterial but also enhanced the selectivity toward H2S. The HS-SDME method was simple to process and required only
a droplet of solvent for analysis to be realized. This HS-SDME-SCN
approach exhibited a calibration graph linearity of between 0.1 and
100 μM and a limit of detection of 65 nM (relative standard
deviations of N% (n = 3) < 4.80).
A comparison with UV–vis spectrophotometry was conducted. The
practical applicability of HS-SDME-SNC was successfully demonstrated
by determining H2S in genuine biosamples (egg and milk).
An innovative array of magnetic coils (the discrete Rogowski coil—RC) with the advantages of flexible structure, miniaturization and mass producibility is investigated. First, the mutual inductance between the discrete RC and circular and rectangular conductors are calculated using the magnetic vector potential (MVP) method. The results are found to be consistent with those calculated using the finite element method, but the MVP method is simpler and more practical. Then, the influence of conductor section parameters, inclination, and eccentricity on the accuracy of the discrete RC is calculated to provide a reference. Studying the influence of an external current on the discrete RC’s interference error reveals optimal values for length, winding density, and position arrangement of the solenoids. It has also found that eccentricity and interference errors decreasing with increasing number of solenoids. Finally, a discrete RC prototype is devised and manufactured. The experimental results show consistent output characteristics, with the calculated sensitivity and mutual inductance of the discrete RC being very close to the experimental results. The influence of an external conductor on the measurement of the discrete RC is analyzed experimentally, and the results show that interference from an external current decreases with increasing distance between the external and measured conductors.
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