Electrical communication between a biological system and outside equipment allows one to monitor and influence the state of the tissue and nervous networks. As the bridge, bioelectrodes should possess both electrical conductivity and adaptive mechanical properties matching the target soft biosystem, but this is still a big challenge. A family of liquid-metal-based magnetoactive slurries (LMMSs) formed by dispersing magnetic iron particles in a Ga-based liquid metal (LM) matrix is reported here. The mechanical properties, viscosity, and stiffness of such materials rapidly respond to the stimulus of an applied magnetic field. By varying the intensity of the magnetic field, regulation within a factor of 1000 of the Young's modulus from ≈kPa to ≈MPa, and the ability to reach GPa with more dense iron particles inside the LMMS are demonstrated. With the advantage of high conductivity of the LM matrix, the functions of the LMMS are not only limited to the soft implanted electrodes or penetrating electrodes in biosystems: the electrical response based on the LMMS electrodes can also be precisely tuned by simply regulating the applied magnetic field.
The extreme state of high friction, severe wear, and oxidation invariably occur in mechanical contacts during high temperature steel processing. The application of lubricant to mitigate the aforementioned hindrances can enhance the process performance effectively. Melt lubricants are regarded as a highly promising class due to their good thermal stability and unique physical chemistry. The present study evaluates tribological responses of an alkaline metal borate on steel tribo-pair at 800 °C by ball-on-disk testing. It has been found that the borate melt significantly reduces the friction coefficient and the wear loss in accompany with providing excellent oxidation resistance. On the disk, the formation of a bilayered tribofilm dominates synergistic functionalities while the emergence of an ultrafine-grained layer considerably reinforces the interface integrity of the opposing ball. Cross-sectional examinations of the contact interfaces were carried out on both steel counterparts by FIB/STEM. STEM/HAADF-EDS reveal the formation of a boundary film featuring high concentration of B and significant depletion of O superimposed on a Na-rich film on the rubbing disk. On the opposing surface, a chemically complex film consisting of Na, Fe, O, amorphous C and [3] B which resides on nanograins of iron oxide is evidenced by STEM/EELS-EDS.
Microdosimetry is an extremely useful technique, used for dosimetry in unknown mixed radiation fields typical of space and aviation, as well as in hadron therapy. A new silicon microdosimeter with 3D sensitive volumes has been proposed to overcome the shortcomings of the conventional Tissue Equivalent Proportional Counter. In this article, the charge collection characteristics of a new 3D mesa microdosimeter were investigated using the ANSTO heavy ion microprobe utilizing 5.5 MeV and 2 MeV ions. Measurement of the microdosimetric characteristics allowed for the determination of the Relative Biological Effectiveness of the heavy ion therapy beam at the Heavy Ion Medical Accelerator in Chiba (HIMAC), Japan. Well-defined sensitive volumes of the 3D mesa microdosimeter have been observed and the microdosimetric RBE obtained showed good agreement with the TEPC. The new 3D mesa "bridge" microdosimeter is a step forward towards a microdosimeter with fully free-standing 3D sensitive volumes.
PbTe-based thermoelectric materials are good candidates for harvesting waste heat at mid-range temperatures due to their high thermoelectric efficiencies. Excellent quality and reliability of the bonding between the thermoelectric material and the electrode at high temperatures are essential for manufacturing thermoelectric generators. Here, a technique has been developed to achieve high-quality bonding between PbTe and the electrode. We have successfully performed one-step sintering of nickel electrode to n-type PbTe powder using spark plasma sintering. The fabricated interphase, composed of nickel telluride, is continuous and homogeneous across the junction, without visible flaws on the electrode or in the interphase and PbTe. To evaluate the long-term thermal stability of the fabricated bond, an aging test was conducted at 823 K for 360 h under vacuum. The microstructures and chemical composition of the fabricated bonding and the aged sample were investigated in detail by scanning electron microscopy equipped with energy dispersive X-ray spectroscopy analysis. No excess reaction was observed between the electrode and the thermoelectric material after aging, supporting the formation of a chemically stable interphase, which acts as a diffusion barrier. Degradation of the PbTe was detected after aging, however. The fabricated interface meets the required criteria for maximum efficiency of PbTe materials.
Herein we investigate a (001)-oriented GaAs1−xBix/GaAs structure possessing Bi surface droplets capable of catalysing the formation of nanostructures during Bi-rich growth, through the vapour-liquid-solid mechanism. Specifically, self-aligned “nanotracks” are found to exist trailing the Bi droplets on the sample surface. Through cross-sectional high-resolution transmission electron microscopy the nanotracks are revealed to in fact be elevated above surface by the formation of a subsurface planar nanowire, a structure initiated mid-way through the molecular-beam-epitaxy growth and embedded into the epilayer, via epitaxial overgrowth. Electron microscopy studies also yield the morphological, structural, and chemical properties of the nanostructures. Through a combination of Bi determination methods the compositional profile of the film is shown to be graded and inhomogeneous. Furthermore, the coherent and pure zincblende phase property of the film is detailed. Optical characterisation of features on the sample surface is carried out using polarised micro-Raman and micro-photoluminescence spectroscopies. The important light producing properties of the surface nanostructures are investigated through pump intensity-dependent micro-PL measurements, whereby relatively large local inhomogeneities are revealed to exist on the epitaxial surface for important optical parameters. We conclude that such surface effects must be considered when designing and fabricating optical devices based on GaAsBi alloys.
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