Liquid crystal nanoscience, a field exploring the mutually beneficial combination of the unique properties of nanoscale materials and fluid, yet ordered liquid crystalline phases, is increasingly focusing on semiconductor quantum dots. In one major research thrust, the anisotropic properties of the liquid crystal host are sought to facilitate the assembly of quantum dots into arrays, in another, both size-and shape-dependent optical and electronic properties of quantum dots are used to manipulate optical, electro-optical and alignment properties of liquid crystalline materials. This feature article reviews recent accomplishments and new insights in this fascinating area of soft matter nanocomposites including work from our laboratory on a series of CdSe and CdTe quantum dots as additives in nematic liquid crystal hosts.
Ink‐jet printing of monolayer‐capped gold nanoparticles is introduced as a versatile and highly efficient means to pattern the alignment of nematic liquid crystals. Any homeotropic alignment patterns can be created quickly ranging in size from 30 μm (850 dpi) to several square inches, with high accuracy that does not deteriorate with time. Depending on the alignment underlayer, intermediate configurations between homeotropic and homogeneous are also feasible. Nematic liquid crystals with both positive and negative dielectric anisotropy can be switched by applying a DC or AC electric field in the printed vertical domains with the substrate configuration determining the electro‐optic response.
Ink‐jet printing of monolayer‐capped nanoparticles is introduced as a versatile and highly efficient means to pattern the alignment of nematic liquid crystals. As discussed by Torsten Hegmann and co‐workers on page 257, any homeotropic alignment patterns that can be switched by applying AC or DC electric field can quickly be created with high accuracy ranging in size from a few micron (>850 dpi) to several square inch.
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