Biodiesel is one of the promising renewable sources to fulfill the future energy demand of the world. Sustainable feedstock for biodiesel production is one of the major criteria to ensure the process of renewability. Chicken fat is an encouraging feedstock for biodiesel. In this study, waste chicken fat was converted to biodiesel via catalysed transesterification. Optimised process parameters were recorded at 1:4 oil-to-methanol volume ratio and 0.5 wt% KOH catalyst concentration with a biodiesel yield of 96%. The FT-IR spectral analysis of chicken fat and chicken fat biodiesel confirmed the conversion of chicken fats into biodiesel. The physico-chemical properties of biodiesel were tested in accordance with ASTM D6751 and EN 14214 biodiesel standards. The specific fuel properties of chicken fat biodiesel that include calorific value, viscosity and acid value were found to be lower than that of petrodiesel. The diesel engine performance tests confirmed that the biodiesel blends performance was similar to petrodiesel. It is noted that while the brake horsepower increased with the increase of biodiesel blending percentage, the engine power output was found to decrease. Specific fuel consumption also increased along with the biodiesel blending percentage.
Heterogeneous catalyst has been viewed as a promising catalyst for biodiesel production. This study employed Turritella terebra (TT) shell as a source for synthesizing heterogeneous CaO catalyst for biodiesel production via transesterification by utilizing chicken fat as a feedstock. The TT shell CaO catalyst was characterized and its catalytic performance was studied. The spectrographic methods that include FTIR, SEM, PSA, and BET-BJH were employed for characterization of the synthesized CaO. The TT shell CaO catalyst optimally produced chicken fat biodiesel (CFB) with reaction parameters at catalyst concentration of 4 wt%, chicken fat to methanol molar ratio of 1:12, reaction temperature of 60°C, and reaction time of 90 min. The optimal yield was 94.03% and the TT shell CaO catalyst still yield 79.19% of CFB on the fifth cycle of reaction. This study has implied that TT shell is a feasible and attractive renewable source of heterogeneous CaO catalyst for biodiesel production.
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