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The success of improved oil recovery from natural fractured chalk fields by injection of water depends largely on the wetting conditions of the reservoir rock and also, to some extent, on the compaction due to water weakening of the formation. Samples from outcrops are often used to mimic the reservoir properties in laboratory work. The present study illustrates that care must be taken when selecting outcrop material; in particular, the content of silica will affect these important properties. Chalk samples from Aalborg, which contained significant amounts of silica and minor amounts of clay (6.3 wt% Si), were studied by SEM and the mineral properties of the silica characterized. The surface chemistry of the porous medium was different from chalk containing smaller amounts of silica and clay (1.4–2.8 wt%). In the presence of a crude oil with high acid number and initial formation water, the water-wet fraction of Aalborg chalk remained close to 1.0 after aging for four weeks at 90°C in the crude oil. The Amott–Harvey wetting index showed, however, the wetting condition to be close to neutral, and only small amounts of water and oil imbibed spontaneously at the residual saturations. The difference in wetting conditions due to different content of silica and clay is also reflected in differences in the mechanical properties. It appeared that the mechanical strength, as studied by a large number of tests, became weaker as the water wetness decreased. The effect of wettability on the water weakening of chalk is discussed in terms of chalk dissolution and the chemistry associated with thin water films. As an overall conclusion and recommendation, a careful comparison should be made of the Si-content in the reservoir rock and outcrop chalk when picking material for laboratory experiments.

Climate changes preserved in sandstones are documented by comparing the sediment composition and early diagenetic changes in sandstones deposited during arid to semi-arid conditions, the Skagerrak Formation, with sandstones of the Gassum Formation deposited in a humid well-vegetated environment. The study area covers the easternmost part of the Norwegian-Danish Basin, for which the Fennoscandian Shield functioned as sediment source area. The depositional environments of the formations, their distribution and burial depths are well-constrained, facilitating a comprehensive petrographical and geochemical study complemented by porosity and permeability measurements of cores widely distributed in the basin (1700 to 5900 m burial depth). The Skagerrak Formation had an immature composition with more abundant feldspar, rock fragments and a larger variability in the heavy mineral assemblage when compared to the Gassum Formation, which was characterized by quartz and more stable heavy minerals. The arid to semi-arid climate led to early oxidizing conditions under which abundant iron-oxide/hydroxide coatings formed, while the evaporative processes occasionally resulted in caliche and gypsum precipitation. Under the humid climate, kaolinite precipitated due to leaching of feldspar and mica, and the abundant organic matter caused reducing conditions, which led to other Fe-rich phases, i.e. pyrite, Fe-chlorite and siderite. The inherited early diagenetic pore fluids and mineral assemblage also affect the mineral changes occurring during deeper burial, so dolomite preferentially formed in the sandstones deposited in an arid environment, while ankerite characterizes sandstones deposited under humid conditions. In addition to climate-induced burial diagenetic changes, there are also temperature-dependent phases, such as illite and quartz cement. Despite the same sediment source area remaining active during the entire period, the sediments that reached the Norwegian-Danish Basin were immature during the arid interval, although mature during the humid period. This has implications for provenance investigations as well as diagenetic investigations of sandstone reservoir quality.

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