A modern and easy procedure performed using the spectrophotometric method and estimating of Ni (II) in alloy samples. Using a ligand 1-((4-(1-(2-hydroxyphenylimino) ethyl)phenyl)diazenyl)naphthalene-2-ol (HPEDN) and a synthesis of the azo-schiff reaction by reaction p-aminoacetophenone with 2-naphtol in first step and reaction of product with 2-aminonaphthol, Ligand and its complex were identification by using UV-Vis. Spectrophotometry (326nm for ligand (HPEDN), 516nm for complex(Ni-HPEDN)), FT-IR, 1H-NMR, and 13C-NMR. The optimal conditions in the complex composition were studied at pH=9, temperature 25°C, and time 15min. The best concentration was found for Ligand (2×10−4 M), Under optimum conditions concentration ranged from (1.1-7.1) μg/mL of Nickel(II) were obeyed Beer‘s Low, with Molar Absorptivity 0.2648×104L.mol−1.cm−1. Limit of Detection(LOD) and Limit of Quantification(LOQ)were 0.3928 and 1.3082μg.mL−1 respectively. The stoichiometric composition of the chelate is 1:2 (Ni:HPEDN). This method is Sensitive, accurate and rapid spectrophotometric method. The results obtained were compared with flame atomic absorption spectrometry method and results are in conformity.

Remazol Brilliant Blue dye is a noxious dyes, so the snail shell powder was used as a adsorbent surface because of its high efficiency to remove the remazol brilliant blue dye from aqueous solutions where the removal percent was (99.09%). Also, the factors affect the efficiency of adsorption (equilibrium time, adsorbent weight, PH, ionic strength, temperature and using "Langmuir, Freundlich and Temkin" modelels were studied. The experimental data of isotherm showed that it is in good agreement with the freundlich and temkin equation it to take the form (S-curve) according to the Giles classification, and it does not agree with the Langmuir equation. The thermodynamic functions (ΔS, ΔH, ΔG) were calculated and explained in the mean of the chemical structure of the adsorbant.

This study was included using the walnut husks powder as efficient adsorbent material to remove the Azure C dye from its aqueous solution. the effects of (pH), contact time, temperature and the adsorbent quantity were evaluated. the highest adsorption efficiency 98.17% was recorded with 5 ppm of dye according to the law of Beer Lambert (calibration curve for dye), 0.02g of adsorbent material 10 min as contact time and 328 K. The removal data using Freundlich, Langmuir and Temkin models were analyzed at various temperature varying from 298 to 328 K, and the adsorption thermodynamic parameters were studied. In which ΔG values indicates spontaneous process, ΔH refers to endothermic property of the adsorption process and ΔS prove increase in randomness at the solid/solution interface.

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This study was included (Snail shell modification) snail shell melamine formaldehyde polymer (SSMFP). It is an effective adsorbent to remove Azure A dye from aqueous solution. The effects of pH, contact time, ionic strength, temperature and amount of adsorbents were evaluated. The highest adsorption efficiency was recorded at 93.90% with 5 mg/L dye according to the Beer Lambert (Dye Calibration Curve), 0.0050 g of adsorbent 10 minutes contact time and 298 K. Elimination data using Temkin, Langmuir and Freundlich models were analyzed at different temperatures ranging from 298 to 338 K, and the adsorption thermodynamic parameters were studied. Where ΔG values indicate an automatic process, ΔH indicates the exothermic property of the adsorption process and ΔS proves an increase. The adsorption surface was also studied and diagnosed by FT-IR, X-RD, AFM, and SEM technologies