The modification of epoxy composites through the construction of nanostructures via self-organization of block copolymers has become a hot topic. In this research, high toughness epoxy thermoset was prepared through constructing wormlike-nanostructure by incorporating amphiphilic polydimethylsiloxane-block-poly(ε-caprolactone) block copolymer. The fracture toughness of subsequent epoxy thermosets increased nearly 355% comparing with neat epoxy with the addition of 40 wt % wormlike nanostructure, which was higher than that of thermosets with spherical nanostructure (142%). There was obviously plastic deformation in fractured surfaces of thermosets with wormlike nanostructure, it is believed that a combination of several toughening mechanisms leads to the improvement in fracture toughness. The morphologies transition, dynamic mechanical properties and wetting behavior of the thermoset containing spherical/wormlike nanostructures are also reported.
The gradient phenomenon is commonly seen in nature, and the gradual changes in structure could make materials with unique excellent performances compared with homogeneous materials. In this study, a novel approach to prepare damping structural integration epoxy thermosets has been developed. The damping mechanism was systematically discussed through TEM, SAXS, DSC, and DMA. It is shown that the damping property was obviously improved via the gradient plasticization at nanometer scale. Dynamic mechanical analysis showed that when the content of poly(ε-caprolactone)-b-polystyrene was 40 wt %, the glass transition temperature was decreased from 171.66 to 107.84 °C while the damping temperature range (tan δ > 0.2) of the composites was broadened from 28.02 to 52.95 °C. Meanwhile, the tensile properties of epoxy thermosets were also improved when the concentration of poly(ε-caprolactone)-b-polystyrene diblock copolymer was below 20 wt %. It is expected this method could provide a new idea to fabricate damping structural integration materials in the future.
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