It has been suggested that Earth's current supply of water was delivered by asteroids, some time after the collision that produced the Moon (which would have vaporized any of the pre-existing water). So far, no measurements of water ice on asteroids have been made, but its presence has been inferred from the comet-like activity of several small asteroids, including two members of the Themis dynamical family. Here we report infrared spectra of the asteroid 24 Themis which show that ice and organic compounds are not only present on its surface but also prevalent. Infrared spectral differences between it and other asteroids make 24 Themis unique so far, and our identification of ice and organics agrees with independent results that rule out other compounds as possible sources of the observed spectral structure. The widespread presence of surface ice on 24 Themis is somewhat unexpected because of the relatively short lifetime of exposed ice at this distance ( approximately 3.2 au) from the Sun. Nevertheless, there are several plausible sources, such as a subsurface reservoir that brings water to the surface through 'impact gardening' and/or sublimation.

We propose that several short-duration events observed in past stellar occultations by Chiron were produced by ring material. Some similarities between these events and the characteristics of Chariklo's rings could indicate common mechanisms around centaurs. From a reanalysis of the stellar occultation data in the literature, we determined two possible orientations of the pole of Chiron's rings, with ecliptic coordinates λ = (352 ± 10)• , β = (37 ± 10)• . The mean radius of the rings is (324 ± 10) km. One can use the rotational lightcurve amplitude of Chiron at different epochs to distinguish between the two solutions for the pole. Both solutions imply a lower lightcurve amplitude in 2013 than in 1988, when the rotational lightcurve was first determined. We derived Chiron's rotational lightcurve in 2013 from observations at the 1.23 m CAHA telescope, and indeed its amplitude was smaller than in 1988. We also present a rotational lightcurve in 2000 from images taken at the CASLEO 2.15 m telescope that is consistent with our predictions. Out of the two poles, the λ = (144 ± 10)• , β = (24 ± 10)• solution provides a better match to a compilation of rotational lightcurve amplitudes from the literature and those presented here. We also show that using this preferred pole orientation, Chiron's long-term brightness variations are compatible with a simple model that incorporates the changing brightness of the rings while the tilt angle with respect to the Earth is changing with time. Also, the variability of the water ice band in Chiron's spectra as seen in the literature can be explained to a large degree by an icy ring system whose tilt angle changes with time and whose composition includes water ice, analogously to the case of Chariklo. We present several possible formation scenarios for the rings from qualitative points of view and speculate on why rings might be common in centaurs. We also speculate on whether the known bimodal color distribution of the centaurs could be due to centaurs with rings and centaurs without rings.

The surfaces of the large Uranian satellites are characterized by a mixture of H2O ice and a dark, potentially carbon-rich, constituent, along with CO2 ice. At the mean heliocentric distance of the Uranian system, native CO2 ice should be removed on timescales shorter than the age of the Solar System. Consequently, the detected CO2 ice might be actively produced. Analogous to irradiation of icy moons in the Jupiter and Saturn systems, we hypothesize that charged particles caught in Uranus' magnetic field bombard the surfaces of the Uranian satellites, driving a radiolytic CO2 production cycle. To test this hypothesis, we investigated the distribution of CO2 ice by analyzing near-infrared (NIR) spectra of these moons, gathered using the SpeX spectrograph at NASA's Infrared Telescope Facility (IRTF) (2000 -2013). Additionally, we made spectrophotometric measurements using images gathered by the Infrared Array Camera (IRAC) onboard the Spitzer Space Telescope (2003 -2005). We find that the detected CO2 ice is primarily on the trailing hemispheres of the satellites closest to Uranus, consistent with other observations of these moons. Our band parameter analysis indicates that the detected CO2 ice is pure and segregated from other constituents. Our spectrophotometric analysis indicates that IRAC is not sensitive to the CO2 ice detected by SpeX, potentially because CO2 is retained beneath a thin surface layer dominated by H2O ice that is opaque to photons over IRAC wavelengths. Thus, our combined SpeX and IRAC analyses suggest that the near-surfaces (i.e., top few 100 microns) of the Uranian satellites are compositionally stratified. We briefly compare the spectral characteristics of the CO2 ice detected on the Uranian moons to icy satellites elsewhere, and we also consider the most likely drivers of the observed distribution of CO2 ice.

Context. The population of known large trans-neptunian objects (TNOs) is growing very fast and the knowledge of their physical properties is a key issue to understand the origin and evolution of the Solar System. Aims. In this paper we studied the surface composition of the recently discovered TNO 2005 FY 9 , one of the largest known TNOs (∼0.7 times the diameter of Pluto, i.e. 1600 km, if the albedo is similar, or 3100-1550 km in diameter assuming an albedo range 0.2 < p V < 0.8).Methods. We report visible and near infrared spectra covering the 0.35-2.5 µm spectral range, obtained with the 4.2 m William Herschel Telescope and the Italian 3.58 m Telescopio Nazionale Galileo at "El Roque de los Muchachos" Observatory (La Palma, Spain). Results. The spectrum of this large TNO is similar to that of Pluto, with an infrared region dominated by very prominent absorptions bands formed in solid CH 4 . At wavelengths shorter than 0.6 µm, the spectrum is almost featureless and red. The red color most likely indicates the presence of complex organics, as has been hypothesized for Pluto and many other TNOs. The icy-CH 4 bands in this new giant TNO are significantly stronger than those of Pluto, implying that methane could be even more abundant on its surface. The existence of a volatile such as methane on the surface of 2005 FY 9 , likely accompanied by N 2 and CO ices, coupled with its large size, make this Pluto-like TNO an excellent candidate to have an atmosphere comparable to Pluto's.

Context. The study of asteroids that present sporadic cometary activity is of fundamental importance to address several astronomical problems including the end states of comet nuclei, the abundance of water in main belt asteroids, and its role as a possible source of terrestial water. Aims. We studied the composition of the surface of asteroid (3200) Phaethon, a paradigmatic case of asteroid-comet transition object, in order to determine its cometary or asteroidal nature. Methods. We report visible and near infrared spectra covering the 0.35-2.4 µm spectral range, obtained with the 4.2 m William Herschel Telescope, the 2.5 m Nordic Optical Telescope, and the Italian 3.58 m Telescopio Nazionale Galileo at "El Roque de los Muchachos" Observatory (La Palma, Spain). Our spectrum is compared with those of meteorite samples and man-made mineral mixtures to determine possible components, modeled using multiple scattering formulations, and also compared with the spectra of comet nuclei and other comet-asteroid transitional objects. Results. Phaethon's spectrum does not show any sharp structure and has a negative slope at wavelengths >0.43 µm, consistent with B-type asteroids. Below 0.43 µm the reflectance decreases. The spectral shape is similar to that of aqueously altered CI/CM meteorites and of hydrated minerals. A surface composition with hydrated silicates is also suggested by the models. A possible spectral variability in the UV is suggested by the avaliable spectra, and is compatible with a slightly different abundance of hydrated silicates. Finally, Phaethon's spectrum shows important differences with the few comet nuclei properly observed at these wavelengths and is similar to the spectra of other peculiar comet-asteroid transition objects. Conclusions. The spectral properties and dynamical properties of (3200) Phaethon support an asteroidal nature rather than a cometary one. Phaethon is more likely an "activated" asteroid, similar to the population of activated asteroids in the Main Belt Comets, than an extinct comet.