Biodegradable foam is an alternative packaging to replace the expanded polystyrene foam packaging currently in use. Starch has been used to produce foam because of its low cost, low density, low toxicity, and biodegradability. Chitosan has been added to improve mechanical properties of product . The effect of variation on chitosan amount and starch types was investigated in this study. The amount of chitosan was varied as 0; 5; 10; 15; 20; 25; and 30 % w/w and starch types were used in this research were cassava, Corn and sago starch. Biodegradable foam was produced by using baking process method, all of material (Starch, Chitosan solution, Magnesium Stearate, Carrageenan, Glyserol, Protein Isolates dan polyvinil alcohol (PVOH) were mixed with kitchen aid mixer. The mixture was poured into mold and heated in an oven at 125 oC for 1 hour. Then, foam was tested for its mechanical properties, water absorption and biodegradability and morphology (SEM). The results show that foam made from sago starch had lower water absortion than those made from cassava and corn starch. While, foam made from cassava starch was more biodegradable than the other foam. Biodegradable foam based sago starch and 30 % w/w of Chitosan adition gave the best performence in tensile stress that is 20 Mpa
Biodegradable foam merupakan kemasan alternatif pengganti styrofoam yang menggunakan bahan baku utama berupa pati sehingga kemasan tersebut dapat terurai secara alami. Namun, produk biodegradable foam yang dihasilkan masih memiliki karakteristik sifat yang rendah. Penelitian ini dilakukan untuk mengetahui pengaruh penambahan konsentrasi kitosan terhadap karakteristik sifat biodegradable foam yang dihasilkan dari pati sagu alami dan termodifikasi menggunakan metode hidrolisis asam – alkohol. Jenis asam yang digunakan pada hidrolisis asam adalah HCl. Konsentrasi kitosan yang ditambahkan pada penelitian ini divariasikan mulai dari 0, 5, 10, 15, 20, 25, 30 % w/w dari pati. Pembuatan biodegradable foam dilakukan menggunakan metode baking process yang dimulai dengan percampuran bahan selain pati sagu termodifikasi, dilakukannya pengadukan hingga campuran menjadi homogen dan mengembang, dan dipanggang didalam oven dengan suhu 125ºC. Analisa pada biodegradable foam adalah analisa daya serap air, analisa kemampuan daya urai dan uji tarik. Hasil penelitian menunjukkan bahwa modifikasi asam – alkohol pada pati sagu tidak mempengaruhi gugus fungsi. Sifat mekanis biodegradable foam yang terbaik pada penelitian ini diperoleh menggunakan pati sagu termodifikasi HCl dan penambahan kitosan sebesar 20% w/w yang memiliki daya serap 4,95 %, densitas sebesar 1.2 g/m3 kemampuan degradasi sebesar 25.12 % dan kekuatan tarik sebesar 1,27 Mpa.Biodegradable foam is an alternative packaging for styrofoam which uses the main raw material in the form of starch so that the packaging can be decomposed naturally. However, the biodegradable foam products produced still have low characteristics. This research is conducted to determine the effect of the addition of chitosan concentration on the characteristics of biodegradable foam properties produced from natural sago and modified sago starch using acid-alcohol hydrolysis method. The type of acid used in acid hydrolysis is HCl. The concentrations of chitosan added in this study are varied from 0, 5, 10, 15, 20, 25, 30% w / w of starch. Biodegradable foam production is carried out by using the baking process method which begins with the mixing of ingredients other than modified sago starch, stirring until the mixture becomes homogeneous and expands, and baked in an oven at 125ºC. The caracterisation of biodegradable foam are water absorption analysis, biodegradability analysis, and tensile test. The results show that modification of acid-alcohol on sago starch do not affect the functional group. The best mechanical properties of biodegradable foam in this research are obtained by using HCl-modified sago starch and addition of chitosan by 20% w / w which have an absorption capacity of 4.95%, density of 0.6 g / m3, degradation ability of 25.12% and tensile strength of 1.27 MPa.
Biodegradable foam is an original packaging as a styrofoam alternative. Sago starch is used to produce biodegradable foam because of its huge amount, low-cost, and high biodegradability. Starch as a prospectus foam material is sensitive to water due to its hydrophilic properties. Thus, improvement is necessary to boost its water resistance capability. Coating the foam with a hydrophobic material prevents water contact with the starch. In this work, Beeswax was used as a coating agent due to its hydrophobicity. The purpose of this work to determine the concentration and time of beeswax coating on the mechanical properties of biodegradable foam. Beeswax was varied at 0, 2, 4, 6, 8, and 10% wt concentration with coating duration process for 30, 60, 90, 120, and 150 seconds. Biodegradable foam was produced by baking process at 80°C for 1 hour 20 minutes. The results showed that the beeswax coating process increases the water resistance, although it does not significantly affect the tensile strength. Beeswax addition as much as 4% wt. for 150 seconds had improved the biodegradable foam properties as much as 1.92%, 73% in 28 days, and 0.09 MPa for water absorption capability, biodegradability, and tensile strength, respectively.
<p class="E-JOURNALAbstractBody">Ketersediaan limbah serbuk gergaji kayu sangat potensial diolah menjadi karbon aktif karena mengandung selulosa dan lignin yang menyebabkan serbuk gergaji kayu dapat mengikat ion logam berat. Pemanfaatan karbon aktif banyak digunakan di berbagai industri, diantaranya sebagai penyerap zat pencemar dan logam berat. Penelitian ini membahas tentang pembuatan dan pemanfaatan serbuk gergaji kayu sebagai karbon aktif (adsorben) melalui pirolisis dan aktivasi kimia. Tujuannya adalah untuk mengetahui pengaruh suhu pirolisis terhadap kualitas karbon aktif yang dihasilkan. Karbon aktif dibuat menggunakan serbuk gergaji kayu yang didehidrasi di bawah sinar matahari. Proses karbonisasi dilakukan dengan metode pirolisis pada suhu 200 °C, 225 °C, 250 °C, 275 °C dan 300 °C selama 1 jam. Hasil proses pirolisis selanjutnya diaktivasi menggunakan aktivator basa kuat (NaOH) dengan konsentrasi 1 N dan waktu aktivasi 3 jam. Berdasarkan hasil penelitian, suhu pirolisis yang menghasilkan kualitas karbon aktif mendekati Standar Industri Indonesia (SII) 0258-88 adalah pada suhu 275 °C. Kualitas karbon aktif yang dihasilkan memiliki kadar air 3 %, kadar abu 10,2 %, kadar <em>volatile matter</em> 23 %, dan kadar <em>fixed</em> <em>carbon </em>63,7 %.</p><p class="StyleE-JournalKeywordsNotItalic"> </p>
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