High performance low temperature polycrystalline silicon (poly-Si) thin film transistors (TFTs) with large grains were created using diode pumped solid state (DPSS) continuous wave (CW) laser lateral crystallization (CLC), employing fabrication processes at 450°C. Field-effect mobilities of 566 cm2/Vs for the n-channel and 200 cm2/Vs for the p-channel were obtained for a thick Si film (100–150 nm) on a 300×300 mm non-alkaline glass substrate. The high performance of the TFTs is attributed to the predominantly (100)-oriented very large grains. With a decreasing Si-film thickness, the grain size decreases, and the surface orientation of the grain changes from (100) to other orientations. These effects lead to reduced field-effect mobility with decreasing Si-film thickness, but it is easy to obtain a high field-effect mobility of over 300 cm2/Vs, even with a 50 nm thick Si film, without special processing techniques. A complementary metal oxide semiconductor (CMOS) ring oscillator was fabricated using a thin Si film 65 nm thick to demonstrate the high circuit performance of CLC poly-Si TFTs by applying the simplest CMOS process technology. A delay of 400 ps/stage at a gate length of 1.5 µm and a supply voltage of V dd=5.0 (V) was produced on a large non-alkaline glass substrate utilizing a fabrication temperature of 450°C. This crystallization method will lead to the fabrication of high-performance and cheap Si-LSI circuits on large non-alkaline glass substrates.

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The effects of various carrier scattering mechanisms on excimer-laser-crystallized polycrystalline silicon (poly-Si) thin film transistors (TFTs) fabricated using 450 °C processes on a glass substrate were studied. Good performance of a separated by ion implanted oxygen (SIMOX) metal–oxide–semiconductor field-effect transistor (MOSFET) with field-effect mobility of 670 cm2/V s and a subthreshold swing value of 0.087 V/dec was obtained using these 450 °C processes. The results showed the formation of a good silicon/silicon dioxide (SiO2) interface that is comparable to that of thermal oxide, as well as the high capability of 450 °C processes. The performance of the above SIMOX-MOSFET is superior to that of excimer-laser-crystallized poly-Si TFTs fabricated using the same 450 °C processes. This shows that poorer performance of poly-Si TFTs is caused by the poor crystalline quality of the poly-Si film. The field-effect mobility is affected little by the in-grain microdefects and surface morphology of the excimer-laser-crystallized poly-Si film, but it is highly sensitive to the grain size. A field-effect mobility of 320 cm2/V s was obtained for an average grain size of 700 nm. The increase in field-effect mobility began to saturate with grain sizes of approximately 1000 nm. It is not necessary to enlarge the grain size beyond the saturation point of the field-effect mobility to improve performance, because the field-effect mobility of an average grain size of 700 nm is limited by phonon scattering, but not by the grain boundary.

We have developed a new silicon (Si) crystallization method that makes it possible to form single-crystalline Si in the channel regions of thin-film transistors (TFTs) on non-alkali glass without introducing thermal damage. The method includes using a frequency-doubled (2!) diode-pumped solid-state (DPSS) Nd:YVO 4 continuous-wave (CW) laser ( ¼ 532 nm). The unique characteristics of this crystallization method are the introduction of a pre-defined thick capping-Si layer on a pre-patterned channel region and laser irradiation from the back surface through the glass substrate. We succeeded in forming 2-mm-wide and 20-mm-long single-crystalline Si in the channel region of a TFT. A high-performance n-channel TFT on a glass substrate was obtained using a 450 C fabrication process. The TFT had a field-effect mobility of 400 cm 2 /Vs, a subthreshold swing of 0.16 V/dec, and a threshold voltage of 0.24 V.