Adsorption refrigeration systems are promising, sustainable solutions for many cooling applications. The operating range and the performance of an adsorption cooling cycle are strongly dependent on the properties of adsorbents, adsorbates, and bed coatings. Therefore, further research and analysis may lead to improved performance of adsorption coolers. In this paper, studies on working pairs using natural refrigerants and the properties of adsorbent coatings were reviewed. The selected working pairs were then thermodynamically characterised and ranked in terms of refrigerant evaporation temperature values. This was found to be a key parameter affecting the applicability of a given adsorbent/adsorbate pair and the value of SCP (Specific Cooling Power), COP (Coefficient of Performance) parameters, which are now commonly used comparison criteria of adsorption chillers. In the analysis of the coating studies, the focus was on the effect of individual parameters on the performance of the cooling system and the effect of using coated beds compared to packed beds. It was found that a fundamental problem in comparing the performance of different cooling systems is the use of different operating conditions during the tests. Therefore, the analysis compares the performance of the systems along with the most important thermodynamic cycle parameters for the latest studies.

In the face of increasing demands with regard to the share of renewable energy sources in the energy mix, adsorption chillers are becoming a potentially important part of the energy transition. A key component of this type of equipment is the heat exchanger in the adsorption bed, the design of which affects both heat and mass transfer. This study includes an analysis of the geometry and materials used to manufacture such heat exchangers. The geometry analysis is mainly based on the evaluation of the impact of the different dimensions of the exchanger components on heat and mass transfer in the bed. The second part of the study focuses on material-related issues where the main emphasis is on the analysis of the thermal inertia of the exchanger. The paper analyses the latest research on the design of exchangers in adsorption beds, mainly from 2015–2021. Currently, the commonly used SCP and COP coefficients and various test conditions do not provide sufficient information for comparative analysis of adsorption bed heat exchangers, so the authors propose to introduce a new index for the evaluation of heat exchangers in terms of the effect of the design parameters on the energy efficiency of an adsorption chiller.

Solar-powered adsorption chillers are a particularly interesting alternative to energy-intensive conventional refrigeration systems. Integration of the adsorption chiller with solar collectors is a very promising concept since the increase in solar radiation coincides with the increased demand for cooling. Such a solution is very economical and environmentally friendly. It also fits in with current trends related to energy policy and sustainable development. The article presents the results of tests conducted for a two-bed adsorption chiller integrated with solar collectors. The tests were performed on selected days of the summer period (July and August) at the KEZO Research Centre PAS in Jablonna (Poland). Based on the results obtained, the performance parameters of the adsorption chiller were determined, and the problems associated with the integration of all components of the system were identified and discussed. The values of the determined Coefficient of Performance (COP) and cooling capacity for the tested adsorption chiller are, depending on the day on which the tests were conducted, from 0.531 to 0.692 and from 5.16 kW to 8.71 kW, respectively. Analysis of the test results made it possible to formulate conclusions related to the design of integrated systems of adsorption chillers with solar collectors.