Properties of samples containing polyurethane (PU), poly(vinyl acetate) (PVAc) and nanosize particles of calcium carbonate (CaCO3) are correlated with concentrations of these components. Interphase phenomena in PU/PVAc/CaCO3 nanohybrids have been studied before, we focus here on wear and scratch resistance. In addition to polymer blends containing CaCO3, the effects of adding CaCO3 with grafted PVAc, and CaCO3 with grafted silane and PVAc in varying ratios are also evaluated. For blends that do not contain the filler, a hypothesis explaining the concentration dependence of friction called the Bump Model is advanced and supported by the experimental results. In particular, we explain how creating a blend containing only 10% of a second polymer results in a dramatic drop of friction of the majority polymer. In single scratch testing, above 3% the filler displays 'its own' resistance to scratching. Chemical modification of the filler results in shallower residual depths--a consequence of improved interaction of the filler with the polymeric matrix. In sliding wear determination, strain hardening is seen for blends as well as for filler-containing composites. In tensile testing, addition of an unmodified filler increases the elongation at break and thus lowers the brittleness; the effect is even larger for chemically modified fillers.

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Purpose The purpose of this paper is to perform a numerical analysis on the static and dynamic behaviors of beams made up of functionally graded carbon nanotube (FG-CNT) reinforced polymer and hybrid laminated composite containing the layers of carbon reinforced polymer with CNT. Conventional fibers have higher density as compared to carbon nanotubes (CNTs), thus insertion of FG-CNT reinforced polymer layer in fiber reinforced composite (FRC) structures makes them sustainable candidate for weight critical applications. Design/methodology/approach In this context, stress and strain formulations of a multi-layer composite system is determined with the help of Timoshenko hypothesis and then the principle of virtual work is employed to derive the governing equations of motion. Herein, extended rule of mixture and conventional micromechanics relations are used to evaluate the material properties of carbon nanotube reinforced composite (CNTRC) layer and FRC layer, respectively. A generalized eigenvalue problem is formulated using finite element approach and is solved for single layer FG-CNTRC beam and multi-layer laminated hybrid composite beam by a user-interactive MATLAB code. Findings First, the natural frequencies of FG-CNTRC beam are computed and compared with previously available results as well as with Ritz approximation outcomes. Further, free vibration, bending, and buckling analysis is carried out for FG-CNTRC beam to interpret the effect of different CNT volume fraction, number of walls in nanotube, distribution profiles, boundary conditions, and beam-slenderness ratios. Originality/value A free vibration analysis of hybrid laminated composite beam with two different layer stacking sequence is performed to present the advantages of hybrid laminated beam over the conventional FRC beam.

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