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Energy conversion technologies, especially for power generation and refrigeration technologies driven by the low temperature heat, are gathering the momentum recently. This paper presents a novel resorption system for electricity and refrigeration cogeneration. Compared with adsorption refrigeration system, resorption refrigeration is characterized as safety and simple structure since there is no ammonia liquid in the system. The cogeneration system is mainly composed of three high temperature salt (HTS) unit beds; three low temperature salts (LTS) unit beds, one expander, three ammonia valves, two oil valves, four water valves and connection pipes. Chemical working pair of MnCl 2 -CaCl 2 -NH 3 is selected. Since scroll expander is suitable for small type power generation system, it is chosen for expansion process. 4.8 kg MnCl 2 and 3.9 kg CaCl 2 impregnated in expanded natural graphite treated with sulfuric acid (ENG-TSA) are filled in the cogeneration system. Experimental results show that maximum cooling power 2.98 kW is able to be obtained while maximum shaft power is about 253 W with 82.3 W average value. The cogeneration system can be utilized for the heat source temperature lower than 170 o C. Total energy efficiency increases from 0.293 to 0.417 then decreases to 0.407 while exergy efficiency increases from 0.12 to 0.16. Nomenclaturec Specific heat (kJ/(kg. o C)) COP Coefficient of performance E Exergy (kJ/kg) Greek letters ΔH Enthalpy of HTS adsorbent Δx Adsorption quantity variation (kg/kg) ρ Density of ammonia (kg/m 3 )

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