No abstract

Carbon nanotubes constitute a novel class of nanomaterials with potential applications in many areas. The attachment of metal nanoparticles to carbon nanotubes is new way to obtain novel hybrid materials with interesting properties for various applications such as catalysts and gas sensors as well as electronic and magnetic devices. Their unique properties such as excellent electronic properties, a good chemical stability, and a large surface area make carbon nanotubes very useful as a support for gold nanoparticles in many potential applications, ranging from advanced catalytic systems through very sensitive electrochemical sensors and biosensors to highly efficient fuel cells. Here we give an overview on the recent progress in this area by exploring the various synthesis approaches and types of assemblies, in which nanotubes can be decorated with gold nanoparticles and explore the diverse applications of the resulting composites.

Calcium carbonate (CaCO3)/polystyrene (PS) nanoparticles (<100 nm) with core–shell structure were synthesized by atomized microemulsion technique. The polymer chains were anchored onto the surface of nano‐CaCO3 through triethoxyvinyl silane (TEVS) as a coupling agent. Ammonium persulfate (APS), sodium dodecyl sulfate (SDS) and n‐pentanol were used as initiator, surfactant, and cosurfactant, respectively. Polymerization mechanism of core–shell latex particles was discussed. Encapsulation of nano‐CaCO3 by PS was confirmed by using transmission electron microscope (TEM). Grafting percentage of core–shell particles was investigated by Thermogravimetric Analyzer (TGA). Nano‐CaCO3/PS core–shell particles were characterized by Fourier transform infrared (FTIR) spectrophotometer and differential scanning calorimeter (DSC). The results of FTIR revealed existence of a strong interaction at the interface of nano‐CaCO3 particle and PS, which implies that the polymer chains were successfully grafted onto the surface of nano‐CaCO3 particle through the link of the coupling agent. In addition, TGA and DSC results indicated an enhancement of thermal stability of core–shell materials compared with the pure nano‐PS. Nano‐CaCO3/PS particles were blended with polypropylene (PP) matrix on Brabender Plastograph by melt process with different wt% of loading (i.e. 0.1–1 wt%). The interfacial adhesion between nano‐CaCO3 particles and PP matrix was significantly improved when the nano‐CaCO3 particles were grafted with PS, which led to increased thermal, rheological, and mechanical properties of (nano‐CaCO3/PS)/PP composites. Scanning electron microscope (SEM) and atomic force microscope (AFM) images showed a perfect dispersion of the nano‐CaCO3 particles in PP matrix. Copyright © 2011 John Wiley & Sons, Ltd.