In this article, the effectiveness of an advanced sludge treatment technology (Wet Oxidation, WO) is presented by analyzing experimental studies at the lab scale and data collected during years of industrial-scale activities. The data showed good performances of WO on COD and VSS removal efficiencies-about 65-70% and 95-98%, respectively-and the effect of operating parameters (i.e., temperature and reaction time) on process efficiencies was highlighted. The energy balance of the WO systems indicated that about 90% of the energy entering the system may be recovered. Finally, a techno-economic assessment showed that WO can be a suitable solution for sludge treatment and minimization.

Nowadays, sewage sludge management represents one of the most important issues in wastewater treatment. Within the European project "ROUTES," wet oxidation (WO) was proposed for sludge minimization. Four different types of sludge were treated in an industrial WO plant: (1) municipal primary sludge (chemical oxygen demand COD: 73.0 g/L; volatile suspended solid VSS: 44.1 g/L); (2) secondary sludge from an industrial wastewater treatment plant (WWTP) without primary sedimentation (COD: 71.8 g/L; VSS: 34.2 g/L); (3) secondary sludge from a mixed municipal and industrial WWTP without primary sedimentation (COD: 61.9 g/L; VSS: 38.7 g/L); and (4) mixed primary (70%) and secondary (30%) municipal sludge (COD: 81.2 g/L; VSS: 40.6 g/L). The effect of process parameters (temperature, reaction time, oxygen dosage) on WO performance was investigated. Depending on operating conditions, VSS and COD removal efficiency varied in the range 80-97% and 43-71%, respectively. A correlation between process efficiency and the initial VSS/TSS (total suspended solids) ratio was highlighted. Furthermore, a mathematical model of WO process for simulating VSS and COD profiles was developed.

Wet Oxidation (WO) of sewage sludge is a chemical oxidation of sludge at high temperatures and pressures by means of an oxygen-containing gas. The liquid stream originated by WO is easily biodegradable, and therefore, the recirculation to the biological Waste Water Treatment Plant (WWTP) may be a feasible solution. However, the WO effluent has a residual organic and nitrogen content so that its treatment may be required when the receiving WWTP has no surplus treatment capacity left. The aim of this research was the assessment of the anaerobic treatability of the WO liquid residue, in order to reduce the organic load to be recirculated to the WWTP, simultaneously promoting energy recovery. For this purpose, the liquid residue obtained during full scale WO tests on two different types of sludge was submitted to anaerobic digestion in a continuous flow pilot reactor (V = 5 L). Furthermore, batch tests were carried out in order to evaluate possible inhibition factors. Experimental results showed that, after the start-up/acclimation period (~130 days), Chemical Oxygen Demand (COD) removal efficiency was stably around 60% for about 120 days, despite the change in operating conditions. In the last phase of the experimental activity, COD removal reached 70% under the following treatment conditions: Hydraulic Retention Time (HRT) = 20 days, Volumetric Organic Loading Rate (VOLR) = 0.868 kg COD/m(3)/day, Organic Loading Rate per Volatile Suspended Solids (OLRvss) = 0.078 kg COD/kg VSS/day, temperature (T) = 36.5 °C, pH = 8. Energy balance calculation demonstrated anaerobic treatment sustainability.

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Today, several technologies and management strategies are proposed and applied in WWTPs to minimise sludge production and contamination and their techno-economic feasibility has to be carefully evaluated. In this work (which is being conducted within the European Union project 'ROUTES'), based on bench results, a mass balance was drawn for a WWTP (500,000 PE), where it was supposed to install a wet oxidation (WO) stage for sludge minimisation. The design of treatment units and the estimation of capital and operation costs were then performed. Subsequently, a procedure for technical-economic assessment was developed. Basically, this procedure consists in the definition and ranking of several technical (e.g., reliability of the technology, complexity and integration with the existing facilities, amount of residues to be disposed of or recovered, etc.) and economic aspects. Preliminary results have shown WO to be a suitable solution for sludge minimisation. Sewage sludge minimisation by means of wet oxidation 235