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The remediation of aqueous effluents containing indigo carmine (IC), a highly toxic indigoid dye used as a textile coloring agent and an additive in pharmaceutical tablets and capsules, was studied using four promising technologies: Ultrasound (US), photo-Fenton (PF), TiO 2 photocatalysis (TiO 2 /UV) and electrochemical oxidation with Ti/IrO 2-SnO 2-Sb 2 O 5 as anode (EO). The main degradation pathway was determined for each system tested. Additionally, the comparative effects of initial pH and presence of chloride ions was investigated. The results showed that EO of IC was mediated by chloride, whereas IC degradation by TiO 2 /UV occurred directly in valence band holes of the catalyst. However, with PF and US systems hydroxyl radicals ᭹ OH played the main role. In spite of the different degradation pathways, acidic pH increased the performance of all systems. The presence of chloride favored the efficiency of EO, but inhibited the IC removal by PF, as well as the elimination of Chemical Oxygen Demand (COD) by US and TiO 2 /UV. The results showed that, under working conditions, EO with Ti/IrO 2-SnO 2-Sb 2 O 5 anodes is the best option to treat IC in effluents containing a significant concentration of chloride ions

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Highlights Pharmaceutical removal using biological digesters, sonication and membrane filtration. Biotransformation of pharmaceutical in biological and ultrasound treatment. Hybrid ultrasound coupled treatment processes with biological reactor and membrane filtration.