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The main scope of this research is to investigate the impact of rotating magnetic field (RMF) on the physical properties of the Sn-0.5Ag-0.5Cu-2.0Sb-0.1Al (SAC0505SbAl) solder alloy. The application of RMF during molten alloy cooling showed prominent effect on the morphology, thermal properties, and the consequent mechanical characteristics. It was shown that the dendritic morphology was changed from columnar dendrites to equiaxed grains with the application of RMF. In addition, RMF processing modified the eutectic phases in the alloy matrix. These notable modifications have resulted in a substantial increase in ductility (* 30%) with a slight decrease in tensile parameters (UTS and YS). Such effects could enhance elastic compliance and plastic energy dissipation ability of solder alloys, which plays superbly fundamental function in drop-impact reliability. Differential scanning calorimetry (DSC) analysis reveals that significant decrease in pasty range (from 10.8 to 7.5°C) and undercooling (from 13.1 to 9.0°C) was attained after applying RMF. The stress exponent (n), the activation energy (Q), and deformation mechanism of the SAC0505SbAl alloy processed with and without RMF were discussed in detail. The obtained results are certainly expected to fill the knowledge gap about the behavior of these recently developed solder alloys under the effect of RMF that are potential alternatives as Pb-free interconnecting material in microelectronic packaging industry.

The design of ligand‐free platinum nanoclusters (PtNCs) for the field of renewable energy is still challenging. Herein, we reported a fast synthesis of ligand‐free Pt nanoclusters (NCs) by utilizing the outer defect of a representative type of zeolitic imidazolate framework (ZIF). Structural investigation suggests a homogenous distribution of the PtNCs on the outer layer of the ZIF‐8 structure. The as‐prepared PtNCs@ZIF‐8 exhibits high catalytic activity for the hydrogen evolution reaction (HER). The extremely low overpotential with 1.4 mV, high kinetic current (specific and mass activity at 50 mV), and larger exchange current density were achieved in acidic solution, better than those of the commercial 20% Pt/C catalysts under the same condition. Furthermore, the PtNCs can be extracted from the ZIF‐8 structure to both aqueous and non‐aqueous solvent, which could be further used for other systems. These findings allow for a simple route of template‐guided NC synthesis and their release.

Zinc (Zn) nanoparticles and (Cu 0.5 Tl 0.5 )Ba 2 Ca 2 Cu 3 O 10δ (CuTl-1223) superconducting phase were prepared separately by sol-gel and solid-state reaction methods, respectively. Zn nanoparticles were added in CuTl-1223 superconducting matrix with different weight percentage during the final sintering process to obtain (Zn) x /CuTl-1223 (x = 0-4 wt%) nanoparticle-superconductor composites. The effect of Zn nanoparticles on structural, morphological, superconducting, and dielectric properties of CuTl-1223 phase was investigated. The addition of these Zn nanoparticles has not affected the crystal structure of host CuTl-1223 superconducting phase. Superconducting properties were enhanced after the addition of Zn nanoparticles up to certain optimum content (i.e., x = 1 wt%), which were due to improved inter-grain connectivity by healing up of micro-cracks and reduction of defects like oxygen deficiencies, etc. The activation energy (U) was increased after the addition of Zn nanoparticles in CuTl-1223 phase. The dielectric properties of these samples (i.e., dielectric constant, dielectric loss) were determined by experimentally measured capacitance (C) and conductance (G) as a function of frequency at room temperature. The addition of metallic Zn nanoparticles in CuTl-1223 matrix has overall suppressed the dielectric parameters of (Zn) x /CuTl-1223 nanoparticlesuperconductor composites. The metallic Zn nanoparticles played a significant role in inter-grain couplings by filling the voids and pores.