The discharge of metals and dyes poses a serious threat to public health and the environment. What is worse, these two hazardous pollutants are often found to coexist in industrial wastewaters, making the treatment more challenging. Herein, we report an EDTA-cross-linked β-cyclodextrin (EDTA-β-CD) bifunctional adsorbent, which was fabricated by an easy and green approach through the polycondensation reaction of β-cyclodextrin with EDTA as a cross-linker, for simultaneous adsorption of metals and dyes. In this setting, cyclodextrin cavities are expected to capture dye molecules through the formation of inclusion complexes and EDTA units as the adsorption sites for metals. The adsorbent was characterized by FT-IR, elemental analysis, SEM, EDX, ζ-potential, and TGA. In a monocomponent system, the adsorption behaviors showed a monolayer adsorption capacity of 1.241 and 1.106 mmol g(-1) for Cu(II) and Cd(II), respectively, and a heterogeneous adsorption capacity of 0.262, 0.169, and 0.280 mmol g(-1) for Methylene Blue, Safranin O, and Crystal Violet, respectively. Interestingly, the Cu(II)-dye binary experiments showed adsorption enhancement of Cu(II), but no significant effect on dyes. The simultaneous adsorption mechanism was further confirmed by FT-IR, thermodynamic study, and elemental mapping. Overall, its facile and green fabrication, efficient sorption performance, and excellent reusability indicate that EDTA-β-CD has potential for practical applications in integrative and efficient treatment of coexistenting toxic pollutants.

BackgroundRecently a new generation of endodontic sealers has been developed based on calcium silicate as MTA Fillapex, Endoseal MTA, Total Fill BC Sealer, EndoSequence BC Sealer, iRoot SP, Endo CPM sealer, MTA-Angelus and ProRoot Endo Sealer. A review of literature was conducted to discuss the composition, physicochemical properties, and clinical perspectives of calcium silicate based sealers.Material and MethodsA literature search was conducted in PubMed and web of knowledge databases with appropriate MeSh terms and keywords. A total of 71 studies were reviewed for data extraction. Results and ConclusionsCalcium silicate based sealers showed suitable physical properties to be used as an endodontic sealer. However, its high solubility remains an important issue. They show good performance regarding calcium ion release, film thickness, and fowability. More researches are required about features of calcium silicate based sealers before recommending them for clinical applications. Key words:Calcium silicate, root canal filling materials, composition, physical properties.

IntroductionIt is very important to obtain a tight seal in obturated root canal, making it necessary to conduct clinical or laboratory studies on the sealability of endodontic materials. Different methodologies have been historically used to assess microleakage of different endodontic materials. The aim of the present study was to comprehensively review different material testing methods used in microleakage studies, their interpretation and importance in endodontic literature.Material and MethodsA systematic search was conducted in Medline, Cochrane, and Web of Science databases. In addition, the reference lists of review articles on the topic were searched. No language restriction was applied. Two independent reviewers screened the article.ResultsMicroleakage is considered the single most important risk factor responsible for apical periodontitis. Dye penetration, dye diffusion, bacterial and endototoxin infiltration, fluid filtration, glucose, caffeine and protein infiltration, radioisotope penetration, animal studies, and electrochemical or 3D evaluation are different methodologies used to assess dental leakage. 91 out of 177 articles in the primary search were included in the study. These methods are very divergent in their viewpoints; that is why their results cannot be easily compared. It is necessary to standardize microleakage detection methods in order to more correctly evaluate the phenomena that are found between the root canal wall and the root canal filling materials.ConclusionsAll the methods are useful if studies are performed strictly with large sample sizes and proper control groups and if the technique can be standardized. Furthermore, more evaluations of the reliability of the methods are strongly recommended. Key words:Dental leakage, review, root canal, material testing methods, data interpretation.

The main objective of this study was to estimate the genetic parameters for body measurement and yearling live bodyweight traits in the Makuie sheep breed. The data set consisted of 2 144 lambs from 122 sires and 984 dams recorded in 21 years from 1989 to 2009 at the Makuie Sheep Breeding and Raising Station (MSBS). The traits that were studied were height at withers, height at rump, body length, heart girth, leg circumference and yearling weight. The analyses were carried out based on an animal model with the restricted maximum likelihood (REML) approach using a derivate-free (DF) algorithm. Six animal models were fitted, differentiated by including or excluding maternal effects, and with and without covariance between maternal and direct genetic effects. Ignoring the maternal effects, the direct heritability was estimated as 0.20, 0.24, 0.10, 0.14, 0.02 and 0.36 for height at wither, height at rump, body length, heart girth, leg circumference and yearling weight, respectively. The estimates were slightly higher when maternal effects, genetic or environmental, were ignored in the analyses. Using bivariate analysis, the estimates for additive genetic correlations ranged from 0.56 to 0.81 among the studied traits. A log-likelihood ratio test (LRT) was used to select the most appropriate univariate model for each trait. Based on LRT, the direct additive genetic and maternal permanent environmental effects were regarded as an important source of variation of the studied traits. The estimates of genetic parameters can be considered a basis for calculating selection indices for body measurements, as well as revealing their association with yearling bodyweight traits.

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