Trace elements diffuse negligible distances through the pristine crystal lattice in minerals: this is a fundamental assumption when using them to decipher geological processes. For example, the reliable use of the mineral zircon (ZrSiO4) as a U-Th-Pb geochronometer and trace element monitor requires minimal radiogenic isotope and trace element mobility. Here, using atom probe tomography, we document the effects of crystal–plastic deformation on atomic-scale elemental distributions in zircon revealing sub-micrometre-scale mechanisms of trace element mobility. Dislocations that move through the lattice accumulate U and other trace elements. Pipe diffusion along dislocation arrays connected to a chemical or structural sink results in continuous removal of selected elements (for example, Pb), even after deformation has ceased. However, in disconnected dislocations, trace elements remain locked. Our findings have important implications for the use of zircon as a geochronometer, and highlight the importance of deformation on trace element redistribution in minerals and engineering materials.

Deformation fabrics in Proterozoic/Cambrian granitic rocks of the Þine nappe, and mid-Triassic granites of the Bozdag nappe constrain aspects of the tectonometamorphic evolution of the Menderes nappes of southwest Turkey. Based on intrusive contacts and structural criteria, the Proterozoic/Cambrian granitic rocks of the Þine nappe are subdivided into older orthogneisses and younger metagranites. The deformation history of the granitic rocks documents two major deformation events. An early, pre-Alpine deformation event (D PA ) during amphibolite-facies metamorphism affected only the orthogneisses and produced predominantly top-to-NE shear-sense indicators associated with a NE-trending stretching lineation. The younger metagranites are deformed both by isolated shear zones, and by a major shear zone along the southern boundary of the Þine submassif. We refer to this Alpine deformation event as D A3 . D A3 shear zones are associated with a N-trending stretching lineation, which formed during greenschistfacies metamorphism. Kinematic indicators associated with this stretching lineation reveal a top-to-south sense of shear. The greenschist-facies shear zones cut the amphibolite-facies structures in the orthogneisses. 207 Pb/ 206 Pb dating of magmatic zircons from a metagranite, which crosscuts orthogneiss containing amphibolite-facies top-to-NE shear-sense indicators, shows that D PA occurred before 547.21.0 Ma. Such an age is corroborated by the observation that mid-Triassic granites of the Þine and Bozdag nappes lack D PA structures. The younger, top-to-south fabrics formed most likely as a result of top-to-south Alpine nappe stacking during the collision of the Sakarya continent with Anatolia in the Eocene.

We present an electron backscatter diffraction, cathodoluminescence, and radiogenic U-Pb dating study of large zircon grains (0.8-1.5 mm) that show evidence of intracrystalline deformation, fracturing, grain size reduction and a large spread in U-Pb ages. The samples are from an amphibolite facies deformation zone within granulite facies anorthositic rocks (Bergen Arc, Norway). Large zircon grains show three main lattice distortion types: (I) distortions with rotations around <001> and an orientation change of ∼0.3 °/µm subparallel to (100); (II) highly distorted, half circular shaped zones located at grain edges with at least 0.8-1°/µm distortions; and (III) low-angle boundary networks forming deformation zones up to 100 µm wide. Types II and III distortions exhibit significant disturbances of the otherwise homogeneous CL signature.Crystal plastic deformation with the slip system [010](100) resulted in type I distortions. Stress concentrations at grain contacts between rheologically hard grains caused localized crystal plastic deformation with minor amount of microfracturing forming type II distortions. Type III distortions formed by crystal plastic deformation often associated with inclusions using several slip systems. Distortions of types I and II show minor and moderate resetting of the original ca. 900 Ma zircon grains, respectively, due to enhanced pipe diffusion along dislocation walls. In type II distortions, accelerated lattice diffusion through the highly distorted crystal lattice, combined with exceptionally high boundary to volume ratio, caused significant chemical disturbance and age resetting to 410 Ma. Fine-grained aggregates contain grains with low internal deformation and an oscillatory zoned CL signature (Z-grains) or high internal deformation and a disturbed CL signature (D-grains). Z-and Dgrains are interpreted to have formed by heterogeneous nucleation and growth, and fracturing along strain-hardened low-angle boundaries present within types I and II, respectively. Z-grains show a clustered chemical signature with a 437 ± 11 Ma age interpreted to directly date the Caledonian amphibolite facies reworking.