Herein, solution‐processed indium gallium zinc oxide (IGZO) thin‐film transistor (TFT) is fabricated utilizing metal nitrates as precursors, and the impact of nitrate ions in different solvents on the performances of IGZO TFT is demonstrated. During IGZO film fabrication, the nitrogen in nitrate species actually dopes into the film in the fashion of different chemical states depending on different solvents. When IGZO precursors dissolve in deionized water (DIW), due to the high polarity of the solvent, metal nitrates are completely dissociated, leading to the conversion of nitrates to nitrides in IGZO film. This nitrogen decreases the density of the interface trap states, thus improving the characteristics of the IGZO TFT. In contrast, when using 2‐methoxyethanol (2‐ME) as the solvent, nitrogen mainly forms nitrogen oxide and acts as a trap density that leads to the degradation of the device performances. By increasing the annealing temperature of IGZO film, nitrogen oxide can convert to metal nitride, resulting in enhanced device performance. The IGZO TFT fabricated using DIW as a solvent with 300 °C annealing temperature exhibits the saturation mobility of 2.5 cm2 V−1 s−1 and Ion/off ratio of >106.5. Herein, a step is made toward the solvent effect on the performance of solution‐processed oxide TFT.

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In the present work, oxalic acid doped molecularly imprinted conducting polyaniline film for melamine detection was prepared by in-situ-electrochemical polymerization on the glassy carbon electrode (GCE) using melamine as template. The optimal monomer/template molar ratio was attained to be 0.2:0.1:0.01 (aniline: oxalic acid: melamine) and molecular recognition properties towards melamine were evaluated by differential pulse voltammetry. Under optimal conditions the imprinted polymer film was used to detect different concentrations of melamine in standard solutions and real milk samples. Compared with the nonimprinted polymer (NIP), the molecularly imprinted polymer (MIP) film showed higher affinity and sensitivity towards melamine with a linear range, quantification limit and detection limit of 0.5-200 nM, 1.375 nM and 0.413 nM respectively. Furthermore, the polymer blend film showed good selectivity toward melamine, stability, reproducibility and practical applications for the determination of melamine in infant formula milk with the recovery of 92.32-102.49%. The doping of the polymer with oxalic acid enhanced the conductivity and sensitivity of the sensor.