Chemical
emissions were characterized for steam-cured cured-in-place-pipe
(CIPP) installations in Indiana (sanitary sewer) and California (stormwater).
One pipe in California involved a low-volatile organic compound (VOC)
non-styrene
resin, while all other CIPP sites used styrene resins. In Indiana,
the uncured resin contained styrene, benzaldehyde, butylated hydroxytoluene
(BHT), and unidentified compounds. Materials emitted from the CIPP
worksites were condensed and characterized. An emitted chemical plume
in Indiana was a complex multiphase mixture of organic vapor, water
vapor, particulate (condensable
vapor and partially cured resin), and liquid droplets (water and organics).
The condensed material contained styrene, acetone, and unidentified
compounds. In California, both styrene and low-VOC resin condensates
contained styrene, benzaldehyde, benzoic acid, BHT, dibutyl phthalate,
and 1-tetradecanol. Phenol was detected only in the styrene resin
condensate. Acetophenone, 4-tert-butylcyclohexanol,
4-tert-butylcyclohexanone, and tripropylene glycol
diacrylate were detected only in the low-VOC condensate. Styrene in
the low-VOC condensate was likely due to contamination of contractor
equipment. Some, but not all, condensate compounds were detected in
uncured resins. Two of four California styrene resin condensates were
cytotoxic to mouse alveolar type II epithelial cells and macrophages.
Real-time photoionization detector monitoring showed emissions varied
significantly and were a function of location, wind direction, and
worksite activity.
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