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This paper presents an experimental study on the evaluation of bridging law for a z-pin. The relationship between the z-pin bridging force and its displacement was measured by z-pin pullout tests. The tests were carried out using three types of samples with: single small pin; 3×3 small-pins (three columns? three rows) and 3×3 big-pins. For 3×3 small-pins samples, a typical pullout curve with initial bonding, debonding and frictional sliding was obtained. A high peak value of the debonding force was reached before z-pin debonding started. After debonding was initiated, the pull-out force dropped rapidly to a lower value, the pins were then pulled out steadily against friction. However, for samples with 3x3 big-pins, it was difficult to discern the peak debonding force. The major results of this study are expected to provide a better physical understanding of the mechanics and mechanisms of z-pin bridging, aside from an efficient and accurate methodology to measure the crack-bridging law.

Toughening of recycled poly(ethylene terephthalate) (PET) was carried out by blending with a maleic anhydride grafted styrene-ethylene/butylene-styrene triblock copolymer (SEBS-g-MA). With 30 wt % of the SEBS-g-MA, the notched Izod impact strength of the recycled PET was improved by more than 10-fold. SEM micrographs indicated that cavitation occurred in just a small area near the notch root. Addition of 0.2 phr of a tetrafunctional epoxy monomer increased the recycled PET melt viscosity by chain extension reaction. Different from the positive effect of the epoxy monomer in toughening of nylon and PBT with elastomers, the use of the epoxy monomer in the recycled PET/SEBS-g-MA blends failed to further enhance dispersion quality and thus notched impact strength. This negative effect of the epoxy monomer was attributed to the faster reactivity of the epoxy group with maleic anhydride of the SEBS-g-MA than with the carboxyl or hydroxyl group of recycled PET.