In the present study, economically viable NiO nanoparticles were produced by biogenic preparation using stevia leaf broth and their in-vitro antioxidant and antimicrobial activities were evaluated. The properties of the prepared NiO nanoparticles were confirmed by analytical techniques such as Ultraviolet-Visible (UV-Vis), X-ray diffraction (XRD), FE-SEM, and Fourier transform infrared spectroscopy (FTIR) analyses. Morphological studies using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that the size of synthesized nanoparticles ranged from 20 to 50 nm, most of which were spherical and few of which were agglomerated. The role of the biological moieties, which reduce and cap the nanoparticles, was studied using FTIR analysis. The prepared nanoparticles strongly inhibited gram-negative bacteria, which is a camper with gram-positive bacteria and fungi. Furthermore, it performs an effective in-vitro activity through α,α-diphenyl-β-picrylhydrazyl (DPPH) reduction. Thus, it can be concluded that the effective and easy green synthesis process used for NiO nanoparticles provides potential antimicrobial agents against multidrug-resistant microbes.
Using simple graphene transfer and the laser lift-off process for a non-centrosymmetric GaN layer on a flexible polydimethylsiloxane (PDMS) substrate, the piezotronic effect by strain-induced current−voltage measurements at the two end points is studied. By inducing compressive strain on the flexible graphene/GaN/PDMS sensor, the Schottky barrier between the graphene and GaN/PDMS heterojunction can be electromechanically modulated by the piezotronic effect. It is observed that the flexible graphene/GaN/PDMS sensor is sensitive to various applied compressive and tensile strains in the positive/ negative bias scans. The sensor is extremely sensitive to a compressive strain of −0.1% with a gauge factor of 13.48, which is 3.7 times higher than that of a standard metal strain gauge. Furthermore, the sharp response of the flexible graphene/GaN/ PDMS sensor under the −0.1% compressive strain is also investigated. The results of this study herald the development of commercially viable large-scale flexible/wearable strain sensors based on the strain-controlled piezotronic effect in future investigations.
Zinc cobaltite (ZnCo2O4) is an emerging electrode material for supercapacitors due to its rich redox reactions involving multiple oxidation states and different ions. In the present work, potato chip-like 0D interconnected ZnCo2O4 nanoparticles (PIZCON) were prepared using a solvothermal approach. The prepared material was characterized using various analytical methods, including X-ray powder diffraction and scanning electron microscopy. The possible formation mechanism of PIZCON was proposed. The PIZCON electrode material was systematically characterized for supercapacitor application. The areal capacitance of PIZCON was 14.52 mF cm−2 at 10 µA cm−2 of current density, and retention of initial capacitance was 95% at 250 µA cm−2 following 3000 continuous charge/discharge cycles. The attained measures of electrochemical performance indicate that PIZCON is an excellent supercapacitor electrode material.
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