The chemistry of metal–organic frameworks (MOFs), a new
class of emerging crystalline porous solids with three-dimensional
(3D) networks composed of metals and multidentate organic molecules,
was introduced by using three differently shaped crystals. We reported
new and mild MOF synthesis methods that are simple and devised to
be performed in high school or primarily undergraduate school settings.
MOF applications were demonstrated by use of our synthesized MOFs
in the capture of iodine as a potentially hazardous molecule from
solution and as a drug delivery system. These applications can be
visually confirmed in minutes. Students can gain knowledge on advanced
topics, such as drug delivery systems, through these easy-to-prepare
MOFs. Furthermore, students can gain an understanding of powder X-ray
analysis and ultraviolet–visible near-infrared spectroscopy.
This laboratory experience is practical, including synthesis and application
of MOFs. The entire experiment has also been recorded as an educational
video posted on YouTube as a free public medium for students to watch
and learn. In this paper we first report the steps we took to synthesize
and analyze the MOFs, followed by a description of a simple demonstration
that we verified to effectively exhibit adsorption by MOFs. We conclude
with a description of how the laboratory activity and demonstration
were implemented in an undergraduate chemistry laboratory.
The merits of three approaches (explicit, reflective and implicit) to Nature of Science (NOS) teaching and learning in the context of a summer research experience on high school student participants' NOS ideas were explored in this study. The effectiveness of explicit over implicit approaches has been demonstrated in school contexts, but less empirical evidence exists regarding the comparative merits of these approaches when the practices that learners engage in are highly authentic in terms of their alignment with professional science and the context where they take place. The Authentic Experiences in Science Program (AESP), a summer program at a major research university, offered a unique context for an investigation of these issues. In the AESP, high school students worked for an extended period of time in a research laboratory on an authentic research project accompanied by out-of-laboratory seminars. A modified form of the Views of Nature of Science (VNOS) Questionnaire was administered to 30 participants of the AESP at the beginning and again at the end of the program. Additionally, six participants experiencing one of the three approaches were interviewed and observed as they participated in laboratory research. Results revealed that the explicit approach was generally more influential in this context. However, some students experiencing one of the other two approaches did exhibit changes in NOS understandings, and these changes seemed to be associated with favorable dimensions of the laboratory placements. These results support the argument that engaging students in highly authentic forms of scientific and engineering practices can be influential as a context for reflecting on NOS. Our results also speak to the power of explicit approaches to NOS teaching and learning when accompanying learner involvement in highly authentic science and engineering research. # 2015
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